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金属矿山 ›› 2022, Vol. 51 ›› Issue (11): 246-251.

• 综合利用 • 上一篇    下一篇

湿磨时间对钢渣泥碳化固结特性的影响机理研究

赵少伟1 李佳洁1,2 倪文1 毛市龙1 齐子函1
  

  1. 1.北京科技大学土木与资源工程学院,北京 100083;2. 山东钢铁股份有限公司,山东 济南 271104
  • 出版日期:2022-11-15 发布日期:2022-12-08
  • 基金资助:
    国家自然科学基金青年基金项目(编号:52004021)

Influence Mechanism of Wet Grinding Time on Carbonization and Consolidation Characteristics of Steel Slag Mud

ZHAO Shaowei1 LI Jiajie1,2 NI Wen1 MAO Shilong1 QI Zihan1   

  1. 1. School of Civil and Resource Engineering,University of Science and Technology Beijing,Beijing 100083;2. Shandong Iron and Steel Co. ,Ltd. ,Jinan 271104,China
  • Online:2022-11-15 Published:2022-12-08

摘要: 磁选回收铁是钢渣利用的有效方法之一,但由此产生的钢渣泥水化活性低,目前尚无有效利用手段。加速碳酸化养护技术对提高钢渣产品的早期强度和体积稳定性有积极作用,通过碳化养护方法研究了不同湿磨时间下钢渣泥碳化块体材料的抗压强度和碳酸化程度,并利用XRD和热重-差热分析阐明强度增强机制。结果表明:① 钢渣泥具有碳化固结特性,其中湿磨60 min钢渣泥碳化固结特性最好,钢渣湿磨有最优的时间,过长时间粉磨不利于碳酸化固结。② 钢渣泥强度与碳酸化程度成正比,在压制成型与碳化养护过程中,水化反应作用微乎其微,碳化产物的生成带来强度的提升。③ 钢渣在湿磨成为钢渣泥的过程中发生了水化反应,且部分水化产物容易与空气中的CO2发生碳酸化反应,生成碳化产物。碳化养护可以使碳酸化反应进行得更为彻底,且碳化产物晶型更为稳定。研究成果为钢渣泥的综合利用提供参考。

关键词: 钢渣泥, 湿磨时间, 抗压强度, 碳酸化程度, 热重-差热分析

Abstract: Iron recover by magnetic separation method is one of the effective methods for the utilization of steel slag,but steel slag mud producted has low hydration activity and there is no feasible means of utilization at present.Accelerated carbonation curing technology has a positive effect on improving the early strength and volume stability of steel slag products.The compressive strength and carbonation degree of steel slag mud carbonated block materials under different wet grinding time were studied by carbonation curing method,and the strength enhancement mechanism was clarified by XRD and TG-DTG analysis.The results showed that:① steel slag mud has carbonation and consolidation characteristics.Among them,the carbonation and consolidation characteristics of steel slag mud are the best after wet grinding for 60 min.The steel slag wet grinding has the best time.Too long grinding is not conducive to carbonation and consolidation.② The strength of steel slag mud is proportional to the carbonation degree.During the process of pressing and carbonization curing,the hydration reaction is very small,and the formation of carbonized products brings about an increase in strength.③ The steel slag undergoes a hydration reaction in the process of wet grinding into steel slag mud,and some of the hydration products are easily carbonated with CO2 in the air to form carbonized products.Carbonation curing can make the carbonation reaction more thorough,and the crystal form of the carbonized product is more stable.The research results provide a reference for the comprehensive utilization of steel slag mud.

Key words: steel slag mud,wet grinding time,compressive strength,carbonation degree,TG-DTG analysis