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金属矿山 ›› 2023, Vol. 52 ›› Issue (07): 213-218.

• 矿物工程 • 上一篇    下一篇

微细粒高岭土对黄铁矿海水浮选的影响机理

王忠红1,2 李育彪1,2 向 焱1,2 杨 旭1,2 李万青1,2
  

  1. 1. 矿物资源加工与环境湖北省重点实验室,湖北 武汉 430070;2. 武汉理工大学资源与环境工程学院,湖北 武汉 430070
  • 出版日期:2023-07-15 发布日期:2023-09-05
  • 基金资助:
    国家自然科学基金面上项目(编号:51974215)。

Influencing Mechanisms of Fine Kaolinite on Pyrite Flotation with Seawater

WANG Zhonghong1,2 LI Yubiao1,2 XIANG Yan1,2 YANG Xu1,2 LI Wanqing1,2 #br#   

  1. 1. Hubei Provincial Key Laboratory of Mineral Resources Processing & Environment,Wuhan 430070, China;2. School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China
  • Online:2023-07-15 Published:2023-09-05

摘要: 为探究海水浮选体系中黏土矿对黄铁矿的影响,进行了不同高岭土含量条件下黄铁矿的浮选分离试验 研究,并通过 Zeta 电位、矿浆泡沫层等测试分析机理。 结果表明:低含量高岭土不影响黄铁矿海水浮选,但高含量高 岭土抑制黄铁矿海水浮选。 机理分析表明:微细粒高岭土泥化罩盖在黄铁矿表面或通过机械夹带进入泡沫中,降低 黄铁矿回收率。 DLVO 理论计算表明:弱酸条件下,高岭土主要通过端面罩盖在黄铁矿表面,而弱碱条件下,主要通过 机械夹带干扰黄铁矿浮选。 研究结果揭示了海水浮选黄铁矿的不利条件,为实现海水高效浮选分离黄铁矿提供了一 定的指导意义,有利于拓展海水等高盐水在矿物浮选领域的应用。

关键词: 高岭土, 黄铁矿, 海水, 浮选

Abstract: In order to investigate the influence of clay minerals on pyrite flotation in seawater,the flotation tests of pyrite were carried out with different kaolinite content. Zeta potential,pulp foam layer and other tests were further conducted to reveal the mechanisms. The results showed that low kaolinite content did not influence pyrite flotation in seawater while high kaolinite content depressed the pyrite flotation in seawater. Further mechanisms indicated that kaolinite slime can readily cover the surface of pyrite particles or form entrainment to enter into concentrate,further reducing pyrite flotation recovery. DLVO theoretical calculation showed that the kaolinite face mainly covered pyrite surface under weakly acidic condition. Differently,kaolinite interfered with pyrite flotation by mechanical entrainment under weakly alkaline conditions. The research revealed the adverse conditions of pyrite flotation in seawater,providing importantly theoretical support to achieve an efficient flotation of pyrite in seawater,which is helpful to expand the application of high saline water such as seawater in the field of mineral flotation.

Key words: kaolinite,pyrite,seawater,flotation