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金属矿山 ›› 2023, Vol. 52 ›› Issue (09): 98-102.

• 矿物工程 • 上一篇    下一篇

新型硫抑制剂 HD12 替代石灰的试验研究

王体琛1,2,3,4 邓久帅1,2,3,4 卢 雨4 孙振武1,2,3,4 朱开顺1 朱萱菲1
  

  1. 1. 中国矿业大学(北京)化学与环境工程学院,北京 100083;2. 有色金属行业三稀资源综合利用工程技术研究中心,北京 100083;3. 有色金属行业共伴生资源分离加工重点实验室,北京 100083;4. 矿业大学(北京)内蒙古研究院,内蒙古 鄂尔多斯 017001
  • 出版日期:2023-09-15 发布日期:2023-11-03
  • 基金资助:
    “ 十四五” 国家重点研发计划项目 ( 编号: SQ2022YFC2900065); 中国矿业大学 ( 北京) 中央高校优秀青年团队项目 ( 编号:2023YQTD03)。

Experimental Study of Novel Surfur Depressant HD12 Replacing Lime

WANG Tichen1,2,3,4 DENG Jiushuai1,2,3,4 LU Yu4 SUN Zhenwu1,2,3,4 ZHU Kaishun1 ZHU Xuanfei1 #br#   

  1. 1. School of Chemical & Environmental Engineering,China University of Mining & Technology-Beijing,Beijing 100083,China;2. Engineering Technology Research Center for Comprehensive Utilization of Rare Earth-Rare Metal-Rare Scattered in Non-ferrousMetal Industry,Beijing 100083,China;3. Key Laboratory of Separation and Processing of Symbiotic-Associated Mineral Resources in Non-ferrous Metal Industry,Beijing 100083,China;4. Inner Mongolia Research Institute, China University of Mining and Technology-Beijing,Ordos 017001,China
  • Online:2023-09-15 Published:2023-11-03

摘要: 内蒙古锡盟地区含锌硫化矿石含锌 1. 46%、含铁 22. 07%。 矿石中主要金属矿物为闪锌矿、磁铁矿、黄 铁矿和磁黄铁矿等,主要脉石矿物为石英、钙铁石榴石、方解石、云母、闪石等。 为解决该矿石浮选过程中大量使用石 灰所导致的安全、环保等问题,采用自主研发的新型硫抑制剂 HD12 替代石灰,开展了浮选试验研究。 在磨矿细度为 -0. 074 mm 占 75%的条件下,通过条件试验确定锌粗选适宜的药剂制度为:HD12 用量 10 g / t,硫酸铜用量 240 g / t,丁 基钠黄药用量 80 g / t。 在此基础上,采用“1 粗 2 精 3 扫”的闭路浮选工艺流程处理该矿石,获得了锌品位 50. 04%、锌 回收率 88. 97%的锌精矿,实现了含锌硫化矿中锌资源的高效回收。 HD12 为硫抑制剂时锌选别指标优异,同时显著 降低了药剂用量,可替代石灰用于闪锌矿与黄铁矿、磁铁矿的分离。

关键词: 石灰, 新型硫抑制剂, 闪锌矿, 黄铁矿, 锌硫分离

Abstract: The zinc sulfide ores in Ximeng area of Inner Mongolia contains zinc of 1. 46% and iron of 22. 07%. The main metallic minerals in ores are sphalerite,magnetite,pyrite and pyrrhotite. The gangue minerals in ores are mainly quartz,calcium iron garnet,calcite,mica and amphibole. In order to solve the safety and environmental problems caused by the large amount of lime used in the flotation process of the ore,an novel surfur depressant HD12 was used to replace lime and the beneficiation experiment was carried out. The appropriate reagent system was determined by condition tests as follow:HD12 of 10 g / t,copper sulfate of 240 g / t,sodium butyl xanthate of 80 g / t in the grinding fineness of -0. 074 mm accountng for 75%. On this basis, the closed-circuit flotation process of " one roughing flotation,two cleaning flotation and three scavenging flotation" was adopted to treat the ore. Finally,the zinc concentrate with Zn grade of 50. 04% and Zn recovery rate of 88. 97% could be obtained. The efficient recovery of zinc resources from the zinc sulfide ores is realized. Using HD12 as a sulfur inhibitor,the zinc separation index is excellent,and the dosage of the reagent is significantly reduced,which could replace lime for the separation of sphalerite from pyrite and magnetite.

Key words: lime,novel surfur depressant,sphalerite,pyrite,separation for zinc and sulfur