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金属矿山 ›› 2024, Vol. 53 ›› Issue (4): 269-.

• 综合利用 • 上一篇    下一篇

低硅铁尾矿制备轻质泡沫混凝土试验研究

韩厚胜1,2 李育彪1,2 潘梦真1,2 陈 坤1,2 张 媛1,2 顾雲翔1,2 薛璐韬1,2 蹇守卫3   

  1. 1. 武汉理工大学资源与环境工程学院,湖北 武汉 430070;2. 矿物资源加工与环境湖北省重点实验室,湖北 武汉 430070; 3. 硅酸盐建筑材料国家重点实验室,湖北 武汉 430070
  • 出版日期:2024-04-15 发布日期:2024-05-19

Experimental Study on Preparation of Lightweight Foamed Concrete by Low Silicon Iron Tailings

HAN Housheng1,2 LI Yubiao1,2 PAN Mengzhen1,2 CHEN Kun1,2 ZHANG Yuan1,2 #br# GU Yunxiang1,2 XUE Lutao1,2 JIAN Shouwei3#br#   

  1. 1. School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China; 2. Hubei Key Laboratory of Mineral Resources Processing and Environment,Wuhan 430070,China; 3. State Key Laboratory of Silicate Materials for Architectures,Wuhan 430070,China)
  • Online:2024-04-15 Published:2024-05-19

摘要: 为解决低硅铁尾矿堆存量大、利用困难等问题,以杨家湾尾矿库内低硅铁尾矿为矿物掺和料,水泥为胶 凝材料,Al 粉为发泡剂,制备轻质泡沫混凝土,并考察了水泥掺量、水料比、发泡剂Al 粉掺量、激发剂CaO 掺量等因素 对泡沫混凝土性能的影响。结果表明:在铁尾矿掺量55%、Al 粉掺量0. 14%、CaO 掺量5%、聚丙烯纤维掺量0. 3%、稳 泡剂掺量0. 25%、水料比0. 55 的条件下,经20±1 ℃恒温恒湿养护28 d,可制备出抗压强度1. 84 MPa、干密度768. 61 kg/ m3、比强度2. 394×10-3 Nm/ kg 的轻质泡沫混凝土,综合性能良好,符合JG/ T 266—2011《泡沫混凝土》之A08 干密 度等级、C1 强度等级要求。机理分析表明:孔隙率的过度提高会破坏制品内部的孔隙结构,对制品强度造成负面影 响;铁尾矿的添加有助于混匀料浆,促进Ca(OH)2 的生成,为料浆进一步创造碱性环境,促进钙矾石、C—S—H 凝胶 等水化产物的生成,其与铁尾矿的交织分布会支撑起孔隙结构,改善力学结构,使泡沫混凝土即使在较低密度下仍表 现出较好的力学性能。

关键词: 低硅铁尾矿 泡沫混凝土 机理 Al 粉 比强度

Abstract: In order to solve the problem of large stock and difficult utilization of low-silicon iron tailings,lightweight foamed concrete was prepared by using low-silicon iron tailings from Yangjiawan tailings reservoir as mineral admixtures,cement as cementitious material and Al powder as foaming agent. The effects of cement dosage,water-to-material ratio,foaming agent Al powder dosage and activator CaO dosage on the performance of foamed concrete were investigated. The results showed that under the condition of iron tailings dosage of 55%,Al powder dosage of 0. 14%,CaO dosage of 5%,polypropylene fiber dosage of 0. 3%,foam stabilizer dosage of 0. 25% and water-to-material ratio of 0. 55,the lightweight foamed concrete with compressive strength of 1. 84 MPa,dry density of 768. 61 kg/ m3 and specific strength of 2. 394×10-3 Nm/ kg could be prepared after curing 28 days of constant temperature and humidity at 20±1 ℃. The comprehensive performance was good,which met the requirements of A08 dry density grade and C1 strength grade of JG/ T 266—2011 Foamed concrete. The mechanism analysis showed that the excessive increase of porosity would destroy the pore structure inside the products and had a negative impact on the strength of the products. The addition of iron tailings helped to mix the slurry,promoted the formation of Ca(OH)2,further created an alkaline environment for the slurry,and promoted the formation of hydration products such as ettringite and C—S— H gel. The interlaced distribution of these products and iron tailings would support the pore structure and improve the mechanical structure,so that the foamed concrete still showed good mechanical properties even at a low density.

Key words: low-silicon iron tailings,foamed concrete,mechanism,Al powder,specific strength