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金属矿山 ›› 2025, Vol. 54 ›› Issue (6): 87-93.

• 矿物工程 • 上一篇    下一篇

2-十二酮对菱镁矿与石英浮选分离的影响研究

马英强1,2,3   郭思雨1   程贵彬1   黄  鑫1   印万忠   

  1. 1. 福州大学紫金地质与矿业学院,福建 福州 350108;2. 矿物加工科学与技术国家重点实验室,北京 102628; 3. 福建省新能源金属绿色提取与高值利用重点实验室,福建 福州 350108
  • 出版日期:2025-06-15 发布日期:2025-07-09
  • 作者简介:马英强(1983—),男,副教授,博士,硕士研究生导师。
  • 基金资助:
    国家自然科学基金项目(编号:52374259,51804081);矿物加工科学与技术国家重点实验室开放基金项目(编号:BGRIMM-KJSKL2023-11);云南省重大科技专项计划项目(编号:202302AF080004)。 

Mechanism of 2-dodecanone on Flotation Separation of Magnesite and Quartz 

MA Yingqiang 1,2,3   GUO Siyu 1   CHENG Guibin 1   HUANG Xin 1   YIN Wanzhong   

  1. 1. Zijin School of Geology and Mining,Fuzhou University,Fuzhou 350108,China;2. State Key Laboratory of Mineral Processing Science and Technology,Beijing 102628,China;3. Fujian Key Laboratory of Green Extraction and High-value Utilization of New Energy Metals,Fuzhou 350108,China
  • Online:2025-06-15 Published:2025-07-09

摘要: 为提高菱镁矿与石英的浮选分离效果,在以十二胺为捕收剂的浮选体系下,通过纯矿物与人工混合矿 浮选试验,探究了有机调整剂 2-十二酮对菱镁矿与石英浮选分离的影响。 结合接触角测试、Zeta 电位分析、红外光谱 和 X 射线光电子能谱分析等手段对 2-十二酮的浮选作用机理进行了探讨。 研究结果表明,2-十二酮主要以静电作用 吸附在菱镁矿表面,并伴有一定程度的化学吸附,增强了菱镁矿表面的亲水性,扩大了与石英之间疏水性的差异,并 且使菱镁矿表面正电性增强,进一步阻碍了捕收剂十二胺的吸附,对菱镁矿产生抑制作用。 而 2-十二酮在石英表面 无明显吸附,对十二胺的吸附未产生影响,从而能够实现菱镁矿与石英的高效浮选分离。 

关键词: 调整剂 2-十二酮 , 菱镁矿 , 石英 , 选择性抑制

Abstract: In order to improve the flotation separation of magnesite and quartz,the effect of organic modifier 2-dodecanone on the flotation separation of magnesite and quartz was investigated through single mineral flotation and artificial mixed ore flotation tests under the flotation system of dodecylamine collector. And the mechanism of action of 2-dodecanone was analyzed by combining the contact angle test,zeta potential analysis,infrared spectroscopy and X-ray photoelectron spectroscopy analysis. The results showed that 2-dodecanone adsorbs on the magnesite surface through electrostatic interactions,accompanied by a certain degree of chemical adsorption,which enhances the hydrophilicity of the magnesite surface and enlarges the hydrophobicity difference with quartz,and enhances magnesite surface positive electricity,which further hinders the adsorption of the collector dodecylamine and inhibits the effect on magnesite. 2-dodecanone has no obvious adsorption on the surface of quartz and has no effect on the adsorption of dodecylamine,which can realize the high-efficiency flotation separation of magnesite and quartz.

Key words: modifier 2-dodecanone,magnesite,quartz,selective inhibition 

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