欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2025, Vol. 54 ›› Issue (6): 94-99.

• 矿物工程 • 上一篇    下一篇

湘西某光伏玻璃用石英砂提纯试验研究

都世杰1,2   乔恒芳1,2   李克尧1,2   刘  诚1,2   杨思原1,2    

  1. 1. 武汉理工大学资源与环境工程学院,湖北 武汉 430070; 2. 关键非金属矿产资源绿色利用教育部重点实验室,湖北 武汉 430070
  • 出版日期:2025-06-15 发布日期:2025-07-09
  • 通讯作者: 杨思原(1990—),男,教授,博士,博士研究生导师。
  • 作者简介:都世杰(2000—),男,硕士研究生。
  • 基金资助:
    国家自然科学基金项目(编号:52374276);“十四五”国家重点研发计划项目(编号:2022YFE0126800);中国工程院战略研究与咨询项 目(编号:2024-DFZD-01)。

Experimental Study on the Purification of Quartz Sand for Photovoltaic Glass in Western Hunan Province 

DU Shijie 1,2   QIAO Hengfang 1,2   LI Keyao 1,2   LIU Cheng 1,2   YANG Siyuan 1,2    

  1. 1. School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China; 2. Key Laboratory of Green Utilization of Key Non-metallic Mineral Resources,Ministry of Education,Wuhan 430070,China
  • Online:2025-06-15 Published:2025-07-09

摘要: 湘西某石英砂矿石的 SiO2 含量高达 99. 01%,主要杂质 Fe2O3 、Al 2O3 、TiO2 含量分别为 0. 082%、0. 64% 和 0. 03%,超过光伏玻璃用硅质原料二级品含量要求。 为确定该矿石的开发利用工艺,在工艺矿物学研究基础上进 行了碎磨—强磁选—酸浸工艺技术研究。 结果表明:① 矿样呈碎屑状,颗粒大小多在 2. 0 ~ 0. 5 mm;岩屑由次角状次圆状石英砂屑和少量斜长石碎屑组成;石英砂屑间存在微量的褐铁矿、黄铁矿、金红石等矿物,泥质物以绢云母为 主,Al 主要来源于斜长石、绢云母,Ti 主要来源于金红石,Fe 主要来源于各类铁矿物。 ② 碎至 2~ 0 mm 矿样中的 0. 71 ~0. 074 mm 粒级(产率为 73. 40%)与产率为 17. 68%的 2~ 0. 71 mm 粒级的磨矿合格粒级合并,采用高梯度强磁选机 (背景磁感应强度 1. 7 T)除铁,再在硫酸与氢氟酸的质量比为 2 ∶1、液固质量比为 1 ∶1、浸出时间为 5. 0 h、浸出温度为 65 ℃的情况下酸浸,最终获得 SiO2 含量为 99. 83%、Fe2O3 含量为 0. 007 7%、Al 2O3 含量为 0. 049%、TiO2 含量为 0. 002 0%的石英精矿,满足产品质量要求。 

关键词: 光伏用砂 , 石英提纯  , 磨矿  , 高梯度强磁选 , 酸浸 

Abstract: The SiO2 content of a quartz sand ore in Western Hunan Province is as high as 99. 01%,and the main impurities Fe2O3 ,Al 2O3 and TiO2 contents are 0. 082%,0. 64% and 0. 03%,respectively,exceeding the requirements for the content of secondary products of siliceous raw materials for photovoltaic glass. In order to determine the development and utilization process of this ore,the crushing and grinding-strong magnetic separation-acid leaching process technology research was carried out on the basis of process mineralogy research. The results showed that:① the ore samples are in the form of chips,the particle size is mostly in the range of 2. 0~ 0. 5 mm;The chips are composed of sub-angular-sub-circular quartz sand chips and a small amount of plagioclase feldspar chips;There are trace amounts of limonite,pyrite,rutile and other minerals in between the quartz sand chips;The mud is mainly composed of sericite;The main source of Al is plagioclase feldspar,sericite;The main source of Ti is rutile;The main source of Fe is various types of iron minerals. ② The 0. 71~ 0. 074 mm grains in the crushed to 2~ 0 mm ore samples (with a yield of 73. 40%) were combined with the mill-qualified grains of 2 ~ 0. 71 mm grains with a yield of 17. 68%,and the iron was removed by using a high-gradient strong magnetic separator (with a background magnetic induction intensity of 1. 7 T). The quartz concentrate with SiO2 of 99. 83%,Fe2O3 of 0. 007 7%,Al 2O3 of 0. 049%,and TiO2 of 0. 002 0% was finally obtained under acid leaching at a sulfuric acid to hydrofluoric acid mass ratio of 2 ∶1,a liquid to solid mass ratio of 1 ∶1,a leaching time of 5. 0 h,and the leaching temperature was 65 ℃ ,which meets the product quality requirements. 

Key words: photovoltaic sand,quartz purification,grinding,high gradient strong magnetic separation,acid leaching 

中图分类号: