欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2025, Vol. 54 ›› Issue (9): 121-127.

• 矿物工程 • 上一篇    下一篇

微纳米气泡提高某微细粒辉钼矿浮选回收率的 试验研究 

黄业豪1,2,3   姚  佳3   皇锦展1,2   于博文3   杨雅斌1,2   胡展滔3   彭伟军3    

  1. 1. 超纯矿物新材料产业技术研究院,河南 郑州 450016;2. 河南省地质研究院,河南 郑州 450016; 3. 郑州大学化工学院,河南 郑州 450001
  • 出版日期:2025-09-15 发布日期:2025-10-09
  • 通讯作者: 彭伟军(1986—),男,教授,博士,博士研究生导师。
  • 作者简介:黄业豪(1990—),男,工程师,博士。
  • 基金资助:
    河南省 2023 年度科技攻关项目(编号:232102320329)。 

Experiment Study on Improvement of Flotation Recovery Rate of a Fine Molybdenum Ore by Micro-nano Bubbles 

HUANG Yehao 1,2,3   YAO Jia 3   HUANG Jinzhan 1,2   YU Bowen 3   YANG Yabin 1,2      HU Zhantao 3   PENG Weijun 3    

  1. 1. Henan Institute of Ultrapure Mineral Materials,Zhengzhou 450016,China;2. Henan Academy of Geology, Zhengzhou 450016,China;3. School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China
  • Online:2025-09-15 Published:2025-10-09

摘要: 为探究微纳米气泡强化微细粒辉钼矿浮选过程、提高钼回收率的可行性,分别在自来水体系和微纳米 气泡水体系下,进行了浮选条件优化和对比试验,并采用接触角、高速摄像机等表征手段,揭示了微纳米气泡提高微 细粒辉钼矿浮选回收率的作用机理。 研究结果表明,在再磨细度为-20 μm 占 73%,粗选矿浆浓度为 30%、矿浆 pH 值 为 9、水玻璃用量为 600 g / t、巯基乙酸钠用量为 10 g / t、煤油用量为 60 g / t、2#油用量 40 g / t 的条件下,经“1 粗 2 扫 5 精”的全流程浮选闭路试验,在自来水体系下可得到 Mo 品位为 42. 78%、回收率 82. 03%的钼精矿,在微纳米气泡水体 系下可得到 Mo 品位 41. 41%、回收率 88. 71%的钼精矿。 在微纳米气泡体系下,Mo 回收率提高了 6. 68 个百分点。 微 纳米气泡通过增加微细粒辉钼矿的接触角、增强颗粒间的相互作用、提高颗粒与气泡之间的黏附效果来强化浮选过 程,进而提高了辉钼矿的浮选回收率。 本研究为强化微细粒辉钼矿的回收提供了技术参考和理论依据。 

关键词: 微细粒  辉钼矿  微纳米气泡  回收率

Abstract: In order to investigate the feasibility of enhancing the flotation process of fine-grained molybdenite and improving the recovery rate of molybdenum using micro-nano bubbles,flotation conditions were systematically optimized,and comparative tests were conducted in both tap water and micro-nano bubble water systems. The mechanism by which micro-nano bubbles improve the flotation recovery rate of fine-grained molybdenite was elucidated through contact angle and high-speed camera characterization methods. Results indicated that under the following conditions of regrinding fineness of -20 μm accounting for 73%,rougher pulp concentration of 30%,pulp pH value of 9,sodium silicate dosage of 600 g / t,sodium thioglycolate dosage of 10 g / t,kerosene dosage of 60 g / t,and 2# oil dosage of 40 g / t,a closed-circuit flotation test with " one roughing,two scavenging,and five cleaning" stages was performed. Under the tap water system,a molybdenum concentrate with a grade of 42. 78% and a recovery rate of 82. 03% was obtained. In contrast,under the micro-nano bubble water system,a molybdenum concentrate with a grade of 41. 41% and a recovery rate of 88. 71% was achieved,representing an increase of 6. 68 percentage points in Mo recovery rate. Micro-nano bubbles improve the flotation process by increasing the contact angle of fine-grained molybdenite,enhancing interparticle interactions, and boosting particle-bubble adhesion, thereby improving its flotation recovery rate. This study provides a technical reference and theoretical foundation for improving the recovery of fine-grained molybdenite. 

Key words: fine grain,molybdenite,micro-nano bubbles,recovery rate 

中图分类号: