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金属矿山 ›› 2026, Vol. 55 ›› Issue (1): 293-300.

• 矿物材料 • 上一篇    

钢渣骨料碳化动力学及体积稳定性研究

薛 刚1 王喜喜1 王金权1 韩慧超2   

  1. 1. 内蒙古科技大学土木工程学院,内蒙古 包头 014010;2. 中国二冶集团有限公司,内蒙古 包头 014030
  • 出版日期:2026-01-15 发布日期:2026-02-24
  • 通讯作者: 王喜喜(1998—),女,硕士研究生。
  • 作者简介:薛 刚(1968—),男,教授,博士,硕士研究生导师。
  • 基金资助:
    中央引导地方科技发展资金项目(编号:2025ZY0119);国家自然科学基金项目(编号:52468040);2023 年度内蒙古自治区直属高校基
    本科研业务费项目(编号:2023RCTD025)。

Study on Carbonation Kinetics and Volume Stability of Steel Slag Aggregate

XUE Gang1 WANG Xixi1 WANG Jinquan1 HAN Huichao2   

  1. 1. School of Civil Engineering,Inner Mongolia University of Science and Technology,Baotou 014010,China;
    2. China Second Metallurgical Construction Company,Baotou 014030,China
  • Online:2026-01-15 Published:2026-02-24

摘要: 为研究钢渣骨料碳化动力学及其体积稳定性,采用包头本地的转炉钢渣碳化不同时间,计算钢渣的固
碳量,利用一级动力学方程(PFO)、二级动力学方程(PSO)分别建立钢渣骨料碳化动力学模型,分析碳化钢渣骨料的
矿物组成、微观结构和体积稳定性的变化规律,并制备水泥砂浆试件进行压蒸试验,研究不同碳化钢渣掺量(10%、
30%、50%、70%)下试件的体积稳定性。结果表明:钢渣骨料碳化动力学符合PSO 模型,且钢渣粗骨料的拟合效果优
于钢渣细骨料;碳化8 h 后,钢渣的体积稳定性达到较优水平,细骨料压蒸粉化率下降至3. 36%、浸水膨胀率下降至
0. 85%,粗骨料压蒸粉化率下降至1. 42%、浸水膨胀率下降至0. 79%;碳化钢渣在水泥砂浆中的最高替代率显著提升,
细骨料(0. 16~4. 75 mm)最大替代率由30%提升至50%,粗骨料(4. 75~9. 5 mm)最大替代率由10%提升至30%。

关键词: 钢渣骨料 碳化 固碳量 动力学模型 体积稳定性

Abstract: In order to study the carbonation kinetics and volume stability of steel slag aggregate,the carbon fixation amount
of steel slag was calculated by using the local converter steel slag in Baotou for different carbonation time. The carbonation
kinetics model of steel slag aggregate was established by using the first-order kinetic equation (PFO) and the second-order
kinetic equation (PSO) respectively. The mineral composition,microstructure and volume stability of carbonized steel slag aggregate
were analyzed,and the cement mortar specimens were prepared for autoclave test to study the volume stability of specimens
with different contents of carbonized steel slag (10%,30%,50%,70%). The results show that the carbonation kinetics of
steel slag aggregate is more in line with the PSO model,and the fitting effect of steel slag coarse aggregate is better than that of
steel slag fine aggregate. After 8 hours of carbonization,the volume stability of steel slag reached a better level. The autoclaved
pulverization rate of fine aggregate decreased to 3. 36% and the soaking expansion rate decreased to 0. 85%. The autoclaved
pulverization rate of coarse aggregate decreased to 1. 42% and the soaking expansion rate decreased to 0. 79%. The maximum
replacement rate of carbonized steel slag in cement mortar increased significantly. The maximum replacement rate of fine aggregate
(0~4. 75 mm) increased from 30% to 50%,and the maximum replacement rate of coarse aggregate (4. 75~9. 5 mm) increased
from 10% to 30%.

Key words: steel slag aggregate,carbonization,carbon sequestration,dynamic model,volume stability

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