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金属矿山 ›› 2026, Vol. 55 ›› Issue (3): 306-315.

• 矿物材料 • 上一篇    下一篇

微纳米气泡水强化复合固废基免烧陶粒制备及性能研究

郑熊泽浩1 黄永炳1 张 烨1,2 黄慕洋1,2 谢逸飞1 单恒谕1 杨思原1,2 包申旭1,2   

  1. 1. 武汉理工大学资源与环境工程学院,湖北 武汉 430070;2. 关键非金属矿产资源绿色利用教育部重点实验室,湖北 武汉 430070
  • 出版日期:2026-03-15 发布日期:2026-04-02
  • 通讯作者: 黄永炳(1973—),男,副教授,博士,硕士研究生导师。
  • 作者简介:郑熊泽浩(2000—),男,硕士研究生。
  • 基金资助:
    中央高校基本科研业务费专项(编号:104972025RSCrc0005)。

Research on Preparation and Properties of Composite Solid Waste-Based Non-Sintered Ceramsite Enhanced by Micro-Nano Bubble Water

ZHENG Xiongzehao1 HUANG Yongbing1 ZHANG Ye1,2 HUANG Muyang1,2 XIE Yifei1 SHAN Hengyu1  YANG Siyuan1,2 BAO Shenxu1,2#br#   

  1. 1. School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China;
    2. Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources,Minstry of Education,Wuhan 430070,China
  • Online:2026-03-15 Published:2026-04-02

摘要: 雨水污泥、工程渣土是城市雨水管网系统和建筑工程中的典型固态废弃物,其堆存占用大量土地,破坏
地表植被,影响生态平衡。本研究以雨水污泥和工程渣土为主要原料,以珍珠岩为辅助原料,以粉煤灰为助剂制备免
烧陶粒。探究了粉煤灰掺量、氢氧化钠添加量、水玻璃添加量和微纳米气泡水(MNBW)添加量对陶粒性能的影响。
结果表明,制备免烧陶粒的最佳配比为粉煤灰掺量33. 3%,氢氧化钠添加量2. 8%,水玻璃添加量38. 9%,MNBW 添加
量35 mL。在该条件下制备得到的免烧陶粒抗压强度为6. 51 MPa,1 h 吸水率为8. 40%,堆积密度为852. 76 kg/ m3,表
观密度为1 570. 57 kg/ m3。BET 与SEM 分析发现,MNBW 的添加使陶粒BET 比表面积中微孔面积占比从36. 8%增加
到78. 4%,平均孔径从14. 028 1 nm 减少到10. 612 8 nm,能促使陶粒内部形成均匀平整的微观结构,显著减少大孔径
孔隙的存在,转变为许多微孔,增加陶粒抗压强度,有效降低陶粒密度;XRD 分析发现,碱激发反应生成的N-A-S-H
凝胶,有利于提高陶粒的综合物理性能,可为固体废弃物资源化利用制备免烧陶粒提供理论支持。

Abstract: Rainwater sludge and engineering slag soil are typical solid wastes generated from urban stormwater drainage
systems and construction engineering projects. Their stockpiling occupies substantial land resources,damages surface vegetation,
and disrupts ecological balance. This study focused on preparing non-sintered ceramsite using rainwater sludge and engineering
slag soil as primary raw materials,expanded perlite as an auxiliary material,and fly ash as an additive. The effects of
the fly ash contents,sodium hydroxide addition,water glass addition,and micro-nano bubble water (MNBW) addition on the
properties of the ceramsite were investigated. The results indicate that the optimal formulation for preparing non-sintered ceramsite
is fly ash mass contents of 33. 3%,with sodium hydroxide addition of 2. 8%,water glass addition of 38. 9% and MNBW addition
of 35 mL. The compressive strength of non-sintered ceramsite prepared under these condition is 6. 51 MPa,the 1 h water
absorption is 8. 40%,the bulk density is 852. 76 kg/ m3,and the apparent density is 1 570. 57 kg/ m3. BET and SEM analysis
revealed that the addition of MNBW resulted in an increase in the proportion of micropore area within the BET specific surface
area of ceramsite from 36. 8% to 78. 4%,accompanied by a reduction in the average pore diameter from 14. 028 1 nm to
10. 612 8 nm. Moreover,such modifications facilitated the formation of a uniform and compact microstructure inside the ceramsites,
significantly diminishing the presence of large-diameter pores,which were transformed into numerous micropores. These
structural evolutions contributed to an enhancement in the compressive strength of the ceramsites while effectively reducing
their density. XRD analysis revealed that the alkali-activated reaction generated N-A-S-H gel,which contributed to improving
the overall physical properties of the ceramsite. This research provides theoretical support for the resource utilization of solid
wastes in the production of non-sintered ceramsite.

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