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金属矿山 ›› 2026, Vol. 55 ›› Issue (6): 302-311.

• 矿物材料 • 上一篇    下一篇

快硬早强型碱激发固废基高掺量铁尾矿砂砂浆性能试验研究

阴 悦1 魏晓斌2 栗东平2 刘高杰2 赵瑶瑶2   

  1. 1.北京市城市河湖管理处,北京 100043;2.河北工程大学土木工程学院,河北 邯郸 056001
  • 出版日期:2026-07-15 发布日期:2026-07-21
  • 通讯作者: 魏晓斌(1988—),男,讲师,博士。
  • 作者简介:阴 悦(1980—),女,高级工程师。
  • 基金资助:
    中国博士后科学基金项目(编号:2025MD774107)。

Experimental Study on the Performance of Fast-Setting and Early-Strength Alkali-Activated Solid Waste-Based Mortar with High Content Iron Tailing Sand

YIN Yue1 WEI Xiaobin2 LI Dongping2 LIU Gaojie2 ZHAO Yaoyao2   

  1. 1.Beijing Urban Rivers and Lakes Management Office,Beijing 100043,China; 2.School of Civil Engineering,Hebei University of Engineering,Handan 056001,China
  • Online:2026-07-15 Published:2026-07-21

摘要: 为解决应急抢修工程对早期强度高、凝结硬化快的特种建筑材料的需求,同时探索大宗工业固废在建 筑材料中的高值化利用途径,提出利用碱激发技术制备一种高掺量铁尾矿砂砂浆。研究以粉煤灰(FA)和矿渣(GG BFS)为前驱体,铁尾矿砂全部替代天然砂作为细骨料,通过正交试验设计,系统考察了粉煤灰与矿渣质量比、NaOH溶 液浓度、水胶比及胶砂比4个关键因素对新拌砂浆工作性能及硬化砂浆力学性能的影响规律。结果表明:各因素对砂 浆24 h抗压强度的主次影响顺序为FA与GGBFS质量比、NaOH溶液浓度、水胶比、胶砂比;矿渣掺量是主导早期强度 的决定性因素,主要原因在于矿渣能为体系提供丰富的钙源,促进生成大量致密的C-(A)-S-H凝胶。在最佳配合比 下,砂浆24 h抗压强度达到33.69 MPa,表现出优异的快硬早强特性,同时铁尾矿砂掺量达66.7%,实现了固废的高效 资源化利用。本研究为开发兼具优异力学性能和环保效益的应急抢修材料提供了科学依据与技术支持。

关键词: 快硬早强 , 高掺量铁尾矿 , 碱激发 , 工业固废 , 砂浆性能

Abstract: To address the demand for special building materials with high early strength and rapid setting and hardening in emergency repair projects,and to explore high-value utilization pathways for bulk industrial solid waste in building materi als,this study proposes the preparation of a high-volume iron tailings sand mortar using alkali activation technology.The study utilizes fly ash (FA) and ground granulated blast furnace slag (GGBFS) as precursors,with iron tailings sand fully replacing natural sand as the fine aggregate.Through orthogonal experimental design,the effects of four key factors,namely the mass ratio of FA to GGBFS,NaOH solution concentration,water-binder ratio,and mortar-binder ratio,on the workability of fresh mortar and the mechanical properties of hardened mortar were systematically investigated.The results show that the primary and sec ondary influence order of each factor on the 24-hour compressive strength of mortar is the mass ratio of FA to GGBFS,the con centration of NaOH solution,the water-binder ratio and the cement-sand ratio.The GGBFS content is the decisive factor deter mining early strength,mainly because GGBFS can provide a rich calcium source for the system,promoting the formation of a large amount of dense C-(A)-S-H gel.Under the optimal mix ratio,the 24-hour compressive strength of mortar reaches 33.69 MPa,exhibiting excellent rapid hardening and early strength characteristics.Meanwhile,the iron tailings sand content reaches 66.7%,achieving efficient resource utilization of solid waste.This study provides scientific basis and technical support for the development of emergency repair materials with both excellent mechanical properties and environmental benefits.

Key words: rapid hardening and early strength,high-content iron tailings,alkali-activated,industrial solid waste,mortar performance

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