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金属矿山 ›› 2013, Vol. 42 ›› Issue (11): 158-160+163.

• 综合利用 • 上一篇    下一篇

含钒中间渣返回钒渣钠化焙烧提钒研究

李秀敏1,张一敏1,2,黄晶1,刘涛1,包申旭1   

  1. 1.武汉理工大学资源与环境工程学院;2.矿物资源加工与环境湖北省重点试验室
  • 出版日期:2013-11-15 发布日期:2014-01-26

Research of Vanadium Extraction from Vanadium-bearing Intermediate Slag Mixed into Tailings with Sodium Roasting

Li Xiumin1,Zhang Yimin1,2,Huang Jing1,Liu Tao1,Bao Shenxu1   

  1. 1.School of Resources and Environmental Engineering,Wuhan University of Technology;2..Hubei Key Laboratory of Mineral Resources Processing and Environment
  • Online:2013-11-15 Published:2014-01-26

摘要: 为实现提钒尾渣中钒的高效、低耗回收,以某钢铁公司钒渣为原料,采用提钒尾渣酸浸—酸浸液沉钒预富集工艺制得含钒中间渣,研究了中间渣返回量对钒渣钠化焙烧—水浸钒浸出率的影响,并从机理方面探讨了产生这种影响的原因。结果表明:用含钒中间渣替代提钒尾渣返回钠化焙烧提钒,可降低钒渣中含钒尖晶石分解的温度和烧结程度,促进氧气进入矿物内部氧化钒,使尖晶石中的钒更容易与钠盐反应生成可溶性的钒酸钠,最终实现钒的高效、低耗回收。

关键词: 钒渣, 提钒尾渣, 中间渣, 钠化焙烧, 钒水浸率

Abstract: To solve problems in vanadium recovery with high efficiency and low consumption from vanadium-extracted tailings,taking vanadium slags from a steel company as raw material,vanadium-bearing intermediate slag was concentrated by adopting the process of the acid leaching of vanadium-extracted tailings and vanadium deposition with acid leaching solution,and then the influence of the amount of intermediate slags mixed into tailings to the sodium roasting with vanadium-bearing slag and water leaching rate of vanadium was studied. The mechanism of generating this law was discussed. The results showed that the vanadium-bearing intermediate slag replacing the vanadium-extracted tailings back to the process of vanadium extraction with sodium roasting could decrease the decomposition temperature of vanadium-bearing spinel,and reduce the degree of sintering on roasting slag. It also makes the oxidation of vanadium and promote the reaction of vanadium in vanadium-bearing spinel with Sodium carbonate to generate soluble sodium vanadate more easily,and finally realize vanadium recycling with high efficiency and low consumption.

Key words: Vanadium-bearing slag, Vanadium-extracted tailings, Intermediate slag, Sodium roasting, Water leaching rate of vanadium