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金属矿山 ›› 2019, Vol. 48 ›› Issue (07): 70-74.

• 矿物工程 • 上一篇    下一篇

山西某磁选铁精矿浮选脱硫试验

王英姿1,胡义明2,周永诚2   

  1. 1. 太钢集团岚县矿业有限公司,山西 岚县030027;2. 安徽工业大学冶金工程学院,安徽 马鞍山 243002
  • 出版日期:2019-07-15 发布日期:2019-09-17
  • 基金资助:

    基金项目:国家自然科学基金项目(编号:51674001;51774177),省部共建复杂有色金属资源清洁利用国家重点实验室开发基金项目(编号: CNMRCUKF1601)。

Experimental Research on Flotation Desulfurization of a Magnetic Separation Iron Concentrate in Shanxi

Wang Yingzi1,Hu Yiming2,Zhou Yongcheng2   

  1. 1. Taiyuan Iron & Steel Group Lanxian Mining Co., Ltd, Lanxian 030027, China; 2. School of Metallurgical Engineering, Anhui University of Technology, Maanshan 243002, China
  • Online:2019-07-15 Published:2019-09-17

摘要: 山西某磁选铁精矿铁品位为65.16%,S含量高达2.62%,主要铁矿物为磁铁矿,占总铁的92.23%;含硫矿物主要为磁黄铁矿和黄铁矿,分别占总硫的53.72%和45.67%,硫在粗粒级(+100目)和细粒级(-325目)的含量相对较高,超过70%的硫分布在-200目粒级。为降低该铁精矿中的硫含量,进行了反浮选脱硫试验。结果表明,试样采用1粗1精—粗选与精选尾矿合并扫选,扫选精矿返回粗选的闭路浮选流程处理,在粗选+精选丁基黄药用量为400+100 g/t、H106用量为950+450 g/t、松醇油用量为50+20 g/t的情况下,可获得铁品位为66.59%、含硫0.29%、铁回收率为91.40%的铁精矿和硫品位为22.13%、含铁52.75%、硫回收率为90.07%的硫精矿。

关键词: 磁选铁精矿, 黄铁矿, 磁黄铁矿, 反浮选, 脱硫

Abstract: The iron grade of magnetic separation concentrate is 65.16% and the contents of sulfur is up to 2.62%. The major iron mineral is magnetite, accounting for 92.23% of total iron. The major sulfur minerals are pyrite and pyrrhotite, which account for 53.72% and 45.67% of the total sulfur, respectively. Sulfur is mainly in the coarse fractions (+100 mesh)and fine fractions (-325 mesh), and more than 70% sulfur distributed below 200 mesh. In order to reduce the contents of sulfur, the reverse flotation desulphurization experiments are carried out with iron concentrate. The results showed that the sample is treated with closed-circuit process one roughing and one cleaning-scavenging with tailing of cleaning and scavenging, and concentrate of scavenging returning to roughing. In the case of butyl xanthate dosages of 400 g/t in roughing and 100 g/t in cleaning, H106 dosages of 950 g/t in roughing and 450 g/t in cleaning, and terpenic dosages of 50 g/t in roughing and 20 g/t in cleaning, iron concentrate was obtained with iron grade of 66.59%, sulfur grade of 0.29%, iron recovery rate of 91.40% and sulfur concentrate was obtained with sulfur grade of 22.13%, iron grade of 52.75%, sulfur recovery rate of 90.07%

Key words: Magnetic separation iron concentrate, Pyrite, Pyrrhotite, Reverse flotation, Desulphurization