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金属矿山 ›› 2025, Vol. 54 ›› Issue (10): 97-104.

• 矿物工程 • 上一篇    下一篇

白云鄂博弱磁选铁精矿反浮选脱氟工艺研究

雷梦林1,2,3 刘 杰1,2,3 李 杰1,2,3 张淑敏1,2,3 李艳军1,2,3 朱一民1,2,3   

  1. 1. 矿物加工科学与技术全国重点实验室,辽宁 沈阳 110819;2. 东北大学资源与土木工程学院,辽宁 沈阳 110819;
    3. 难采选铁矿资源高效开发利用技术国家地方联合工程研究中心,辽宁 沈阳 110819
  • 出版日期:2025-10-15 发布日期:2025-11-06
  • 通讯作者: 刘 杰(1981—),女,教授,博士,博士研究生导师。
  • 作者简介:雷梦林(1996—),女,硕士研究生。
  • 基金资助:
    国家自然科学基金项目(编号:52374262);辽宁省科技计划项目(编号:2023JH1/10400011)。

Research on the Process of Defluorination by Reverse Flotation from Weak Magnetic Separation Iron Concentrate of Bayan Obo#br#

LEI Menglin1,2,3 LIU Jie1,2,3 LI Jie1,2,3 ZHANG Shumin1,2,3 LI Yanjun1,2,3 ZHU Yimin1,2,3   

  1. 1. State Key Laboratory of Mineral Processing Science and Technology,Shenyang 110819,China;
    2. School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China;3. National-Local Joint Engineering
    Research Center for High-Efficiency Development and Utilization of Refractory Iron Ore Resources,Shenyang 110819,China
  • Online:2025-10-15 Published:2025-11-06

摘要: 氟是铁精矿中的有害杂质,严重影响钢材性能及冶金过程。为实现白云鄂博磁选铁精矿(TFe 品位
57. 40%、F 含量2. 28%)的提铁降氟,开展了反浮选脱氟试验研究。工艺矿物学表明,氟主要赋存于萤石和氟碳铈矿
中。通过优化矿浆pH、捕收剂和抑制剂种类与用量,确定以油酸钠为捕收剂、玉米淀粉为抑制剂,在常温下采用1 粗
2 精3 扫、中矿顺序返回闭路流程,最终获得铁精矿TFe 品位64. 76%、回收率91. 66%、F 含量0. 178%,脱氟率达
92. 19%。研究为高氟铁矿资源的清洁高效利用提供了可行的技术途径,对类似难处理铁矿石的开发具有参考价值。

关键词: 含氟铁精矿 反浮选脱氟 油酸钠 玉米淀粉

Abstract: Fluorine is a harmful impurity in iron ore concentrate that severely affects steel properties and metallurgical
processes. In order to enhance iron recovery and reduce fluoride content in the Bayan Obo magnetic separation iron concentrate
(TFe grade of 57. 40%,F content of 2. 28%),a reverse flotation defluorination test study was conducted. Process mineralogy
indicated that fluoride is primarily present in fluorite and fluorocarbonatite. By optimizing the pH of the pulp,as well as the
types and dosages of collectors and depressants,sodium oleate was selected as the collector and corn starch as the depressant.
Under normal temperature conditions,a closed-circuit process was implemented featuring one roughing,two cleaning,and three
scavenging,with intermediate products sequentially returned. This ultimately yielded an iron concentrate with TFe grade of
64. 76%,recovery rate of 91. 66%,and F content of 0. 178%,with fluoride removal rate of 92. 19%. This research provides a
feasible technical approach for the clean and efficient utilization of high-fluoride iron ore resources,offering valuable reference
for the development of similarly difficult-to-process iron ores.

Key words: fluoride-containing iron concentrate,defluorination by reverse flotation,sodium oleate,corn starch

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