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金属矿山 ›› 2026, Vol. 55 ›› Issue (9): 198-202.

• 矿物工程 • 上一篇    下一篇

某锂云母浮选尾矿中石英及长石综合回收试验研究

罗志勇1 ,李 钰2 ,邱振忠1 ,孙宁杰3 ,张 寒4 ,郭文达3   

  1. 1.江西永诚锂业科技有限公司,江西 宜春 336300;2.武汉工程大学化学与环境工程学院,湖北 武汉 430205; 3.武汉工程大学兴发矿业学院,湖北 武汉 430073;4.湖北菲利华石英玻璃股份有限公司,湖北 荆州 434000
  • 出版日期:2026-09-15 发布日期:2026-10-15
  • 通讯作者: 郭文达(1991—),男,副教授,博士研究生。
  • 作者简介:罗志勇(1989—),男,工程师。通
  • 基金资助:
    国家自然科学基金项目(编号:52374273,52404427);湖北省科技厅重大科技项目(编号:2025BAA010)。

Experimental Study on Comprehensive Recovery of Quartz and Feldspar From a Lepidolite Flotation Tailings

LUO Zhiyong1 ,LI Yu2 ,QIU Zhenzhong1 ,SUN Ningjie3 ,ZHANG Han4 ,GUO Wenda3   

  1. 1.Jiangxi Yongcheng Lithium Technology Co.,Ltd,Yichun 336300,China; 2.School of Chemistry and Environmental Engineering,Wuhan Institute of Technology,Wuhan 430205,China; 3.Xingfa School of Mining Engineering,Wuhan Institute of Technology,Wuhan 430073,China; 4.Hubei Feilihua Quartz Glass Co.,Ltd.,Jingzhou 434000,China
  • Online:2026-09-15 Published:2026-10-15

摘要: 为实现锂云母浮选尾矿中石英与长石的绿色高效综合回收,本研究以江西某锂云母浮选尾矿为对象, 系统开展工艺矿物学分析与无氟弱酸浮选试验。工艺矿物学分析表明,该尾矿SiO2 含量为77.1%,Na2 O+K2 O含量 为6.9%,其中石英、钠长石和钾长石占比分别为35.3%、44.5%和17.8%,石英与长石总占比超过97%,具备较高的综 合回收价值。浮选试验结果表明,采用自主研发的阳离子捕收剂WIT-1,在磨矿细度为-0.074 mm占50%、矿浆pH值 为4.5、WIT-1用量2.4 kg/t、六偏磷酸钠用量2.2 kg/t的条件下,经1粗7扫反浮选流程,可获得SiO2 品位为99.8% 的高纯石英产品,以及Na2 O+K2 O品位高于9%的长石产品。该方法有效避免了传统氢氟酸活化法和强酸性浮选法 带来的设备腐蚀与环境污染问题,为锂云母浮选尾矿的绿色高效利用提供了可行的技术路径。

关键词: 锂云母浮选尾矿 石英 长石 浮选分离 无氟弱酸浮选 WIT-1捕收剂

Abstract: To achieve the green and efficient comprehensive recovery of quartz and feldspar from lepidolite flotation tail ings,this study systematically conducted process mineralogical analysis and fluorine-free weak-acid flotation tests on a lepido lite flotation tailing sample from Jiangxi Province.Process mineralogical analysis shows that the tailings contain 77.1% SiO2 and 6.9% Na2 O+K2 O,with quartz,albite,and potassium feldspar accounting for 35.3%,44.5%,and 17.8%,respectively.The total proportion of quartz and feldspar exceeds 97%,indicating high comprehensive recovery value.Flotation test results demon strate that using the self-developed cationic collector WIT-1 under the conditions of a grinding fineness of -0.074 mm account ing for 50%,pulp pH of 4.5,WIT-1 dosage of 2.4 kg/t,and sodium hexametaphosphate dosage of 2.2 kg/t,a one-stage roug her and seven-stage scavenger reverse flotation circuit can yield a high-purity quartz product with a SiO2 grade of 99.8% and a feldspar product with a Na2 O+K2 O grade exceeding 9%.This method effectively avoids the equipment corrosion and environ mental pollution issues associated with traditional hydrofluoric acid activation and strong-acid flotation methods,providing a fea sible technical pathway for the green and efficient utilization of lepidolite flotation tailings.

Key words: lepidolite flotation tailings,quartz,feldspar,flotation separation,fluorine-free weak-acid flotation,WIT-1 col lector

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