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金属矿山 ›› 2008, Vol. 38 ›› Issue (04): 134-138.

• 安全与环保 • 上一篇    下一篇

宁明膨润土对水中铜离子的吸附行为

莫伟1,2,韩跃新1,马少健2,苏秀娟2,廖芳艳2   

  1. 1.东北大学;2.广西大学
  • 收稿日期:2007-02-20 出版日期:2008-04-15 发布日期:2011-07-20
  • 基金资助:

    国家自然科学基金项目(编号:50464001),广西“新世纪十百千人才工程”专项基金项目(编号:2005212)。

Adsorption Behavior of Ningming Bentonite for Copper Ions in aqueous solution

Mo Wei1,2,Han Yuexin1,Ma Shaojian2,Su Xiujuan2,Liao Fangyan2   

  1. 1.Northeastern University;2.Guangxi University
  • Received:2007-02-20 Online:2008-04-15 Published:2011-07-20

摘要: 为开发广西宁明膨润土资源在重金属离子废水治理方面的用途,研究了该膨润土对水溶液中Cu2+的吸附行为。静态吸附试验结果表明,该膨润土对Cu2+的吸附速率快,吸附平衡时间短,单位质量吸附量随温度、溶液初始Cu2+浓度及一定范围内溶液初始pH值的提高而增加;试验数据与有关数学模型的拟合结果表明,吸附动力学特性符合准二级动力学方程,等温吸附特性更符合Langmuir等温式;热力学参数计算结果表明,吸附过程为自发的吸热过程。

关键词: 宁明膨润土, 铜离子, 吸附行为

Abstract: In order to develop the use of Guangxi Ningming betonite resource in treating heavy metal ions-containing waste water, the adsorption behavior of this betonite for the Cu2+ in aqueous solution was studied.The static adsorption test results indicate that this betonite has a rapid adsorption rate for Cu2+, and needs a short time to reach the adsorption equilibrium.The unit mass adsorption amount increases with the increase of the temperature, initial Cu2+concentration and initial pH value in certain range.The fitting result between the test data and the relevant mathematical mode shows that the adsorption kinetics characters accord with the pseudo -second order kinetic equation, and the isothermal adsorption characters conform to Langmuir reaction isotherm.The thermodynamic parameter calculation results indicate that the adsorption process is a spontaneous endothermic process.

Key words: Ningming betonite, Copper ions, Adsorption behavior