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Metal Mine ›› 2014, Vol. 43 ›› Issue (05): 82-86.

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Reverse Flotation of the Mixed Magnetic Concentrate of Qidashan Iron Mine by a New Anion Collector DL-1

Zhu Yimin,Li Wei,Zhao Ningning,Luo Binbin,Xia Xiwen   

  1. College of Resource and Civil Engineering,Northeastern University,Shenyang 110819,China
  • Online:2014-05-15 Published:2014-09-11

Abstract: DL-1 is a newly anionic reverse flotation collector developed by Northeastern University.In order to test the floating properties,mixed magnetic concentrate from Qidashan Dressing Plant with Fe grade of 46.02% was used to make reverse flotation tests,and the mechanism in quartz reverse flotation by DL-1 is discussed with Zeta potential measurement and infrared spectrum analysis.The results showed that:①Iron concentrate with Fe grade of 65.38%,recovery of 89.56% was obtained through closed-circuit reverse flotation flowsheet of one roughing,one scavenging,and middles back to the flowsheet in turn with normal temperature and DL-1 as collector; DL-1 can endure temperature changes,and high efficiently collecting quartz at a lower dosage of CaCl2.②There are electrostatic repulsion between quartz and DL-1 with pH of 9~12 in aqueous alkaline solution,and can be weakened by activation of CaCl2 to quartz; electrostatic/chemical adsorption may occur between quartz activated by Ca2+ and DL-1 with pH of 9~11.45,there are strong electrostatic attraction of quartz activated by Ca2+ to DL-1 with pH>11.45,therefore DL-1 can well adsorb and collect quartz at pH range of 9~11.45.③There are physical adsorption,hydrogen bond and chemical adsorption coexist between DL-1 and quartz surface with pH of 11.45,DL-1 can also well collect quartz without Ca2+ activation.

Key words: Anionic collector DL-1, Quartz, Mixed magnetic concentrate, Reverse flotation, Mechanism