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Metal Mine ›› 2015, Vol. 44 ›› Issue (07): 147-151.

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Treating Simulative Wastewater Containing Nickel by Spouted Bed Electro-deposition Method

Chen Xi,Xu Xinyang,Zhao Bing,Xing Jialiang   

  1. College of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China
  • Online:2015-07-15 Published:2015-08-06

Abstract: In order to find out the feasibility in dealing with Ni2+ containing wastewater with constant current spouted bed particle electro-deposition method,the technical conditions optimization research has been conducted with simulated acid Ni2+ wastewater.The results are as follows:①with the increase of pH value,the removal rate of Ni2+ and current efficiency increased first and then decreased; with the increase of current value,the removal rate of Ni2+ increased,current efficiency decreased; both removal rate of Ni2+ and current efficiency decreased as the temperature increased; ②DO value increased with the increase of pH and current value,while decreased with temperature.Blowing nitrogen effectively reduced the DO value.③Blowing nitrogen prevented the nickel deposited back to dissolve,also weakened the concentration polarization which could result in the decline of the Ni2+ removal rate and current efficiency.④under the conditions of Ni2+ concentration 1 g/L,pH=4.5,particle size 1.8 mm,current intensity 15 A,electrolyte temperature 25 ℃ and blowing N2 for 180 min,the removal rate of Ni2+ was 74.77%,the average current efficiency was 67.67%,which were higher by 28 and 16.66 percentage points than that without N2 respectively.Since electro-deposition can directly obtain nickel metal from wastewater,this method has remarkable economic and environmental benefits in practice,and also can be set as a pretreatment method before ion exchange and membrane separation.

Key words: Electro-deposition, Spouted bed, Removal rate of Ni2+, Current efficiency, DO value