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Metal Mine ›› 2019, Vol. 48 ›› Issue (07): 189-193.

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Research on Dynamic Adsorption and Desorption of T-42 Resin on Ammonia Nitrogen in Vanadium Precipitated Wastewater

Zheng Qiaoqiao1,Zhang Yimin1,2,3,4,Huang Jing2,3,4,Bao Shenxu1,2,4   

  1. 1. School of Resource and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China;2. Hubei Province Key Laboratory of Mineral Resources Processing and Environment, Wuhan 430070, China; 3. State Key Laboratory of Environmental Protection Mineral Metallurgical Resources Utilization and Pollution Control, Wuhan 430081, China; 4. Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources, Wuhan 430081, China
  • Online:2019-07-15 Published:2019-09-17

Abstract: In order to understand the adsorption effect on ammonia nitrogen in vanadium precipitated wastewater and the recycle ability of T-42 resin, the influence of ratio of height to diameter of ion exchange column, original ammonia nitrogen concentration and series number on adsorption effect were studied,and the isothermal adsorption curve of T-42 resin was analyzed. In addition, the effect of the type, flow rate and concentration of desorbents on ammonia nitrogen desorption were also studied. The results showed that:①The adsorption effect of T-42 resin on ammonia nitrogen was better when the flow rate of wastewater was 9 mL/min and the ratio of height to diameter was 21.0. The adsorption capacity at the penetration point was 21.91 mg/g, and the adsorption capacity at the end point was 34.31 mg/g. The adsorption capacity of resin on ammonia nitrogen increases with original ammonia nitrogen concentration increasing, but the wastewater treated decreases. Wastewater with concentration of ammonia nitrogen 1 999.56 mg/L meets the standard Class One (≤10 mg/L) by two-stage series adsorption. ②The adsorption of ammonia nitrogen by resin matches the Langmuir isothermal adsorption model and the adsorption process is single molecular layer chemical adsorption. The saturated adsorption capacity is 36.845 9 mg/g in 15 ℃, 38.550 5 mg/g in 25 ℃, 40.617 4 mg/g in 35 ℃. The increasing temperature is beneficial to the adsorption. ③In the case of volume concentration of sulfuric acid 18%, flow rate 3 mL/min and desorbent dosage 2.67 bed volumes, the ammonia nitrogen desorption rate of adsorption saturated resin was higher than 99%. T-42 resin can effectively remove ammonia nitrogen from wastewater, and sulfuric acid can desorb and regenerate the resin which adsorbs ammonia nitrogen.

Key words: Vanadium precipitated wastewater, Resin, Ions exchange column, Ammonia nitrogen