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Metal Mine ›› 2021, Vol. 50 ›› Issue (05): 205-210.

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BeneficiationTechnology Study on a Smelting Slag from Copper Bearing Sludge in Guangdong

RAO Jinshan1,2,3    Lü Haozi1,2,3    CHEN Zhiqiang1,2,3    HU Hongxi1,2,3    LIU Yong1,2,3    JIANG Ying1,2,3   

  1. 1. Institute of Resources Comprehensive Utilization, Guangdong Academy of Science, Guangzhou 510650, China;2. State Key Laboratory of Rare Metals Separation and Comprehensive Utilization, Guangzhou 510650, China; 3. Guangdong Provincial Key Laboratory of Mineral Resources Development and Comprehensive Utilization, Guangzhou 510650, China
  • Online:2021-05-15 Published:2021-05-12

Abstract: A smelting slag from containing copper sludge (referred to as copper slag in the following) contains 3.50% copper, which mainly exists in the form of the metal copper and Cu-Ni-Sn alloy. The dissemination particle size of copper material is not uniform, of which the refractory particle size of -0.01mm accounts for about 55%.The flotation process of copper slag was studied, and the effects of grinding fineness,roughing pH and butyl xanthate dosage on flotation indexes were investigated. The open-circuit comparison tests between whole-grain flotation and sieving and flotation processes were also carried out.The results showed that under the condition of grinding fineness of 85.76% accounting for -0.075 mm with butyl xanthate as collector and terpenol oil as foaming agent, the copper concentrate with copper grade of 20.56% and copper recovery of 65.98% can be obtained by full-grain open-circuit flotation.The copper concentrate with copper grade of 15.65% and copper recovery of 56.52% and +0.15 mm product with copper grade of 22.56% and copper recovery of 18.63% were finally obtained by sieving and flotation. The comprehensive recovery of copper reached 75.15%, and the copper grade of tailings was reduced to 0.49%.The middles of the whole-grain closed circuit flotation are easy to accumulate, and the sieving and flotation closed circuit test process is stable. The final +0.15 mm product and flotation concentrate have a comprehensive copper recovery of 85.15% and a copper grade of 11.90%, which meet the smelting requirements of the furnace.

Key words: copper-bearing sludge, copper smelting slag, screening, flotation