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Metal Mine ›› 2025, Vol. 54 ›› Issue (12): 124-130.

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Efficient Separation of a High-Potassium Collophane Ore in Hubei by Reverse Flotation

XU Changming1,2 HE Dongsheng1,2 TANG Yuan1,2 TIAN Chengtao1,3 LIAO Qiushi3   LI Zhili1,2 FU Yanhong1,2   

  1. 1.School of Resources and Safety Engineering,Wuhan Institute of Technology,Wuhan 430074,China; 2.State Key Laboratory of Green and Efficient Development of Phosphorus Resources,Guiyang 550014,China; 3.Hubei Sanning Chemical Co.,Ltd.,Wuhan 443200,China
  • Online:2025-12-15 Published:2025-12-31

Abstract: To address the challenge of utilizing a high-potassium,medium-low-grade phosphate ore from Hubei,this study initiated with a systematic process mineralogical investigation to elucidate its mineral composition and dissemination character istics.The results indicated that the valuable mineral is primarily fluorapatite,with gangue minerals dominated by K-feldspar, quartz,and a minor amount of dolomite.These gangue minerals are intricately disseminated and closely associated with fluorap atite.Furthermore,the ore contains a high proportion of fine particles smaller than 38 μm.Based on these findings,a combined beneficiation process of "pre-removal of iron,reverse flotation for desiliconization,and reverse flotation for magnesium removal" was developed,employing butyl xanthate,ether-amine collector H-1,phosphoric acid,and fatty acid collector GW-01 as key re agents.Closed-circuit tests yielded a concentrate with a P2 O5 grade of 31.96% and a recovery of 86.78%.The contents of K2 O,SiO2 ,MgO,and sesquioxide (Al2 O3 +Fe2 O3 ) in the concentrate were reduced to 0.99%,8.98%,0.54%,and 2.06%, respectively.This process successfully demonstrates the efficient recovery and utilization of this refractory high-potassium collo phane ore.

Key words: collophane,high-potassium phosphate ore,process mineralogy,reverse flotation,desiliconization

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