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金属矿山 ›› 2008, Vol. 38 ›› Issue (06): 56-61+66.

• 矿物工程 • 上一篇    下一篇

氧化锰矿泥湿法浸出试验研究

沈慧庭,张延军,林乡伟,周波   

  1. 广西大学
  • 收稿日期:2008-04-20 出版日期:2008-06-15 发布日期:2011-07-18

Research on Leaching of Manganese Oxide Slime

Shen Huiting,Zhang Yanjun,Lin Xiangwei,Zhou Bo   

  1. Guangxi University
  • Received:2008-04-20 Online:2008-06-15 Published:2011-07-18

摘要: 以大新锰矿氧化锰矿泥为对象,分别采用价格低廉的硫铁矿和甘蔗渣作还原剂,在酸性条件下进行硫铁矿法还原浸出和甘蔗渣水解法还原浸出试验,结果表明,在适当的工艺条件下,两种方法均能获得95%以上的锰浸出率。将两种浸出液除杂净化后,分别制备出了硫酸锰和碳酸锰产品,两种产品均达到工业合格品要求。动力学研究结果显示:硫铁矿法浸出过程受颗粒表面化学反应控制;甘蔗渣水解法浸出过程前期受化学反应和扩散联合控制,后期受扩散控制。

关键词: 氧化锰矿泥, 硫铁矿, 甘蔗渣, 水解, 还原浸出, 浸出动力学

Abstract: Tests on reduction-leaching of Daxin Mine's manganese oxide slime at acidic condition were carried out, with cheap pyrite and bagasse as the reductant respectively. The results show that in proper technical conditions, both methods can obtain a manganese leaching rate higher than 95%. Manganese sulfate and manganese carbonate were prepared by purifying the two pregnant solutions from the above leaching tests, with both satisfying the requirements for qualified industrial products. The study on the leaching kinetics of both processes indicates that the pyrite leaching process is controlled by the chemical reaction on the particle surface; and the bagasse hydrolysis leaching process is controlled jointly by chemical reaction and diffusion in the early period and by diffusion in the late period.

Key words: Manganese oxide slime, Pyrite, Bagasse, Hydrolysis, Reduction leaching, Leaching kinetics