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金属矿山 ›› 2008, Vol. 38 ›› Issue (07): 34-37+147.

• 矿物工程 • 上一篇    下一篇

紫外可见分光光度法对EPS与金属离子的相互作用的研究

王利,温建康,刘美林   

  1. 北京有色金属研究总院
  • 收稿日期:2008-05-18 出版日期:2008-07-15 发布日期:2011-07-16
  • 基金资助:

    国家“973”课题项目(编号:2004CB619206)。

Study on Interaction between EPS and Metallic Ions by UV Spectrophotometry

Wang Li,Wen Jiankang,Liu Meilin   

  1. Beijing General Research Institute for Nonferrous Metals
  • Received:2008-05-18 Online:2008-07-15 Published:2011-07-16

摘要: 生物冶金技术是一种针对贫、杂、细矿石十分有效的方法,具有传统选冶方法不可比拟的优点。胞外聚合物(Extracellular Polymeric Substances,EPS)对生物冶金过程中的金属硫化矿的溶解有着非常重要的作用。通过紫外分光光度计对硫酸法和甲醛-NaOH法提取的EPS及其与金属离子的作用进行了分析,结果表明胞外聚合物仅与Fe3+发生了络合,从而验证了胞外聚合物是通过与其络合的Fe3+的氧化作用来溶解金属硫化矿物的。

关键词: 生物冶金, EPS, 硫酸法, 甲醛-NaOH法, 紫外分光光度法

Abstract: Bio-hydrometallurgical technology is very efficient for handling poor,complex and fine ores and has advantages that conventional mineral processing and metallurgical methods can't have.Extracellular polymeric substances(EPS)plays a very important role in the extraction of metal ions from sulfide ores in the bio-hydrometallurgical process.Analysis is made of the EPS extracted by sulfuric acid method and the method of formaldehyde plus sodium hydroxide and the function of EPS and metal ions by UV spectrophotometer.The results show that there is only complexation between EPS and Fe3+ ions,thus verifying that it is through the oxidation function of the Fe3+ions in the complex between EPS and Fe3+ ions that EPS enables the metal sulfides to degrade.

Key words: Bio-hydrometallurgy, EPS, Sulfuric acid method, Method of formaldehyde plus sodium hydroxide, UV Spectrophotometry