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金属矿山 ›› 2009, Vol. 39 ›› Issue (02): 75-78.

• 矿物工程 • 上一篇    下一篇

某硫化-氧化混合型铜钴矿浮选工艺研究

欧乐明,尹冰一,冯其明,卢毅屏,张国范   

  1. 中南大学
  • 出版日期:2009-02-16 发布日期:2012-02-02
  • 基金资助:

    * 国家自然科学基金项目(编号:50574101),国家重点基础研究发展规划(973)项目(编号:2007CB613602)。

A Flotation Process for a Sulfide-Oxidized Cu-Co Mixed Ore

Ou Leming,Yin Bingyi,Feng Qiming,Lu Yiping,Zhang Guofan   

  1. Central South University of Technology
  • Online:2009-02-16 Published:2012-02-02

摘要: 某硫化-氧化混合型铜钴矿氧化率高并含有大量的碳质泥,用常规浮选法不能得到好的综合回收效果。通过预先浮选脱泥消除碳质泥对浮选过程的影响,然后对硫化铜钴矿和氧化铜钴矿进行异步浮选,并采用硫化剂强化氧化铜钴矿的浮选效果,试验结果表明,对含铜2.63%、钴0.04%、碳6.63%的原矿,可获得铜品位21.12%、铜回收率高达88.55%,含钴0.116%、钴回收率为31.39%的铜钴精矿。研究还发现,硫化剂硫氢化钠与硫化钠相比更有利于氧化铜钴矿物的硫化浮选。

关键词: 硫化-氧化混合型铜钴矿, 碳质泥, 脱泥浮选, 异步浮选, 硫氢化钠

Abstract: A sulfide-oxidized Cu-Co mixed ore has a high oxidation ratio and contains a large amount of carbonaceous mud and a good comprehensive recovery can't be achieved when it is treated by conventional flotation methods.Pr-desliming by flotation was therefore adopted first to eliminate the influence of carbonaceous mud on the flotation process and then asynchronous flotation was used to treat Cu-Co sulfide ore and oxidized Cu-Co ore.Sulfidizing agent was used to enhance the flotation of oxidized Cu-Co ore.As a result, a Cu-Co concentrate assaying Cu 21.2% at a recovery of as high as 88.55% and Co 0.116% at a recovery of 31.39%was produced from a feed ore containing Cu 2.63%, Co 0.04% and C 6.63%.It is also found that sodium hydrosulfide (NaHS) is more beneficial than sodium sulfide(Na2S) when used as a sulfidizing agent to activate the oxidized Cu-Co ore in flotation.

Key words: Sulfide-oxidized Cu-Co mixed ore, Carbonaceous mud, Desliming by flotation, Asynchronous flotation, Sodium hydrosulfide