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金属矿山 ›› 2010, Vol. 39 ›› Issue (10): 44-47,56.

• 矿物工程 • 上一篇    下一篇

硫化钠在铜铅分离中的应用

孙伟,董艳红,张刚   

  1. 中南大学
  • 出版日期:2010-10-15 发布日期:2010-11-09
  • 通讯作者: 孙伟,410083 湖南省长沙市。
  • 作者简介:孙伟(1973—),男,中南大学资源加工与生物工程学院,博士后,副教授,硕士生导师。
  • 基金资助:

    国家自然科学基金项目(编号:51074184)

Application of Sodium Sulphide in the Separation of Lead-copper

Sun Wei,Dong Yanhong,Zhang Gang   

  1. Central South University
  • Online:2010-10-15 Published:2010-11-09

摘要: 研究了硫化钠对经黄药浮选的铜铅混合精矿的脱药效果,以及脱药后的混合精矿对新型组合抑制剂DW的敏感性;肯定了硫化钠的脱药效果和DW对脱药后的铜铅混合精矿的抑制性差异;应用紫外吸光光度法和溶液化学的方法研究了硫化钠脱药机理。研究结果表明:在试验条件下,硫化钠水解产生HS-与吸附在矿物表面的黄原酸根离子发生竞争吸附,使吸附在矿物表面的黄原酸根离子解吸,是硫化钠对经黄药浮选的铜铅混合精矿具有明显脱药效果的根本原因。

关键词: 黄铜矿, 方铅矿, 硫化钠

Abstract: The investigation on the reagent removal effects of sodium sulfide to copper and lead mixing concentrate by the sensitivity of the new combined inhibitor DW after reagent removal of mixing concentrate were carried out.It was affirmed that it had a remarkable removal effect, and there are some differences in inhabitation of the copper and lead mixing concentrate by DW.With the application of UV spectrophotometry, and solution chemistry method, the reagent removal mechanism of sodium sulfide was studied.The results showed that in the experimental conditions, a competitive adsorption happened between HS-by hydrolysis of sodium sulfide and butyl xanthate ion adsorbed on the surface of the minerals and made the butyl xanthate ion realize desorption.This is the basic reason for that sodium sulfide has a remarkable reagent removal effect on the mixed copper and lead concentrates by xanthate flotation.