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金属矿山 ›› 2011, Vol. 40 ›› Issue (02): 146-148+152.

• 安全与环保 • 上一篇    下一篇

超声波辅助去除铅锌选矿外排废水中的硫化物

曾懋华,龙来寿,奚长生,赵旭光   

  1. 韶关学院
  • 出版日期:2011-02-10 发布日期:2011-02-15
  • 基金资助:

    广东省教育部产学研结合项目(编号:2009B090300186),韶关市科技创新项目(编号:韶科2008-07)

Sulphide Removal from Wastewater of Zinc-lead Beneficiation  with the Assistance of Ultrasonic Wave

Zeng Maohua,Long Laishou,Xi Changsheng,Zhao Xuguang   

  1. Shaoguan University
  • Online:2011-02-10 Published:2011-02-15

摘要: 针对广东韶关某大型铅锌矿选矿外排废水中超标的硫化物,采用超声波辅助下的氧化—混凝沉淀法对其进行去除试验,探讨了氧化剂种类和用量、混凝剂种类和用量及超声波辅助反应时间对S2-去除效果的影响。结果表明:在常温下向该废水中加入用量为20 mg/L的氧化剂H2O2,用量为150 mg/L的混凝剂FeSO4和用量为1.0 mg/L的助凝剂聚丙烯酰胺,在超声波辅助下搅拌反应20 min,S2-离子的去除率可达到95%以上,含量可降到0.14 mg/L以下,废水水质达到国家排放标准。

关键词: 铅锌选矿废水, 氧化—混凝, 超声波, S2-去除率

Abstract: Due to the excessive sulfide in wastewater discharged from large-scale lead-zinc dressing plant,the ultrasound-assisted oxidation-coagulation sedimentation method was used to find out the S2- removal effect with the variation of the type and dosage of the oxidant,the coagulant's type and dosage and the reaction time of ultrasonic.The results showed that: at room temperature,with addition of the oxidant H2O2 of 20 mg/L,and the coagulant FeSO4 dosage of 150 mg/L,coagulant-assisted polyacrylamide of 1.0 mg/L,under the assistance of ultrasonic wave at 20 min stirring,S2- ion removal rate could reach above 95%,and its content can be reduced to 0.14 mg/L below,which leads to the wastewater quality reach the national emission standards.

Key words: Wastewater from lead-zinc beneficiation, Oxidation-coagulation, Ultrasonic wave, S2- removal rate