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金属矿山 ›› 2011, Vol. 40 ›› Issue (03): 165-167.

• 综合利用 • 上一篇    

用活化煤矸石制备新型胶凝材料

王海霞1,2,倪文1,2,黄屹1,2,郑永超3,张静文1,2   

  1. 1.北京科技大学;2.金属矿山高效开采与安全教育部重点实验室;3.北京建筑材料科学研究总院
  • 出版日期:2011-03-10 发布日期:2011-03-11

Preparation of New Cementitious Material with Activated Coal Gangue

Wang Haixia1,2,Ni Wen1,2,Huang Yi1,2,Zheng Yongchao3,Zhang Jingwen1,2   

  1. 1.University of Science and Technology Beijing;2.State Key Laboratory of High-Efficient Mining and
    Safety of Metal Mines,the Ministry of Education;3.Beijing Building Materials Academy of Sciences Research
  • Online:2011-03-10 Published:2011-03-11

摘要: 采用脱硫石膏和分析纯CaO作为活性激发剂,通过3种方式活化北京房山煤矸石,并检测、分析用不同方式活化的煤矸石制成的胶凝材料的强度,进而研究了活性激发剂和混磨方式对试验材料热蚀变活化的影响。运用X射线衍射分析表征了煤矸石活化前后的微观特性;运用胶砂试块强度分析和扫描电镜(SEM)分析表征了煤矸石质胶凝材料的胶凝活性。结果表明:该煤矸石的主要活性来源是粘土类矿物,700 ℃煅烧时煤矸石中的高岭石和绿泥石脱水、分解,生成无定形SiO2和Al2O3,与CaO发生固相反应,湿混工艺下固相反应完全,生成C12A7和C2S两种水硬性活性物质,活化物料具有较高的胶凝活性。

关键词: 煤矸石, 热蚀变, 胶凝活性

Abstract: Taking the desulfurized gypsum and the analytical reagent CaO as activator, Beijing Fangshan coal gangues are activated by three ways, and then the strength of cementitious materials with the activated coal gangue in different ways are detected and analyzed to study the effect of activator and mixed grinding on the thermal alteration and activation of test materials.The microscopic properties before and after the activation of coal gangue are characterized by the X-ray diffraction; the cementitious activity of cementitious materials with coal gangues are characterized by the mortar strength analysis and scanning electron microscopy (SEM).The results showed that the main activity of coal gangue sources from the clay minerals.And the kaolinite and chlorite in coal gangue are dehydrated and broken down at 700 ℃ calcined to generate the amorphous SiO2 and Al2O3 which occurs the solid state reaction with CaO.In wet mixing process, the reaction is finished, and then two hydraulic active substances C12A7 and C2S are generated, both of which own a high cementitious activity.

Key words: Coal gangues, Thermal alteration, Cementitious activity