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金属矿山 ›› 2012, Vol. 41 ›› Issue (10): 140-144.

• 安全与环保 • 上一篇    下一篇

微生物对铀(Ⅵ)铁锰离子在土壤中迁移的影响

吕俊文,张宇,邓钦文,张晓文   

  1. 南华大学环境保护与安全工程学院
  • 出版日期:2012-10-15 发布日期:2012-11-08
  • 基金资助:

    * 国家自然科学基金项目(编号:10975070,51074093)。

Study on Influence of Indigenous Microorganisms on Migration of U (Ⅵ) , Fe and Mn Ions in Soil

Lu Junwen,Zhang Yu,Deng Qinwen,Zhang Xiaowen   

  1. School of Environmental Protection and Safety Engineering,University of South China
  • Online:2012-10-15 Published:2012-11-08

摘要: 为了给退役铀矿山的治理提供理论指导,在某铀矿附近采集未受开采影响的土壤样品并从中分离出微生物,用经过稀释、调pH值的铀矿石浸出试验的浸出液模拟铀矿固废酸性渗滤液,通过土壤柱动态吸附—解吸试验,研究了微生物对渗滤液所含U(Ⅵ)和Fe、Mn离子在土壤中迁移的影响。试验结果显示:有微生物协同时与无微生物协同时相比,土壤对3种离子的吸附量分别提高99.7%、75.2%和48.6%,而解吸时,有微生物土壤中3种离子的解吸率比无微生物土壤分别降低20.4、0.4和41.0个百分点,说明微生物对3种离子在土壤中的迁移有很明显的抑制作用。此外,土壤本身对酸性废水有较强的缓冲作用,与是否含有微生物关系不大。

关键词: 微生物, 铀矿固废酸性渗滤液, 铀(Ⅵ)铁锰离子, 土壤, 迁移

Abstract: In order to provide theoretical guidance to the disposal of the out-of-service uranium mines, soil samples near a uranium mine that are unaffected by mining were collected and extracted microorganisms. The leaching solution obtained by diluting and adjusting pH values of uranium ore was used to simulate the acid leaching seepage of uranium solid waste, and the influence of the microorganisms to migration of U (Ⅵ) , Fe and Mn Ions was investigated by the dynamic adsorption-desorption experiment of the soil column. The results showed that: with microbial synergy, the adsorption amount of the three kinds of ion increased by 99.7%, 75.2% and 48.6%, respectively, comparing that without microbial synergy. Meanwhile, the desorption rate of the three kinds of ions in microbial soil reduced by 20.4%, 0.4% and 41.0% respectively, comparing with that in no microbial soil, indicating that the microorganism significantly inhibited the migration of the three kinds of ions in the soil. In addition, the soil itself has a strong cushioning effect on acidic wastewater, and has less relation with microorganisms.  

Key words: Indigenous microorganisms, Acid seepage of uranium solid waste, U(Ⅵ)-Fe-Mn ions, Soil, Migration