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金属矿山 ›› 2013, Vol. 42 ›› Issue (11): 49-52.

• 矿物工程 • 上一篇    下一篇

新疆某褐铁矿石反浮选抑制剂选择 与抑制机理探讨

刘豹1,刘淼2,孙乾予2,毕迪1   

  1. 1.辽宁工程技术大学矿业学院;2.辽宁工程技术大学研究生院
  • 出版日期:2013-11-15 发布日期:2014-01-26

Discussion on Selection of Inhibitor and its Inhibition Mechanism for Reverse Flotation of a Limonite Ore in Xinjiang

Liu Bao1,Liu Miao2,Sun Qianyu2,Bi Di1   

  1. 1.School of Mining Engineering,Liaoning Technical University;2.School of Graduate,Liaoning Technical University
  • Online:2013-11-15 Published:2014-01-26

摘要: 为改善新疆某褐铁矿石反浮选效果,对其反浮选抑制剂进行了优选试验,并通过对矿石中褐铁矿纯矿物在3种不同淀粉类抑制剂情况下的表面ζ电位的测定,研究了这些抑制剂的抑制机理。结果表明:①在酸性环境下羧甲基淀粉钠、普通可溶性淀粉、叔胺盐型阳离子淀粉的抑铁效果逐渐减弱;在碱性环境下叔胺盐型阳离子淀粉、普通可溶性淀粉、羧甲基淀粉钠的抑铁效果逐渐减弱。②在pH=5的矿浆中,以羧甲基淀粉钠为抑制剂,采用1粗2精1扫,中矿顺序返回流程处理该矿石,可获得铁品位为6079%、铁回收率为7996%的铁精矿。③酸性环境下表面带正电的褐铁矿物大量吸附羧甲基淀粉钠(阴离子淀粉),因而羧甲基淀粉钠抑铁效果较好;碱性环境下表面带负电的褐铁矿物大量吸附叔胺盐型阳离子淀粉,因而叔胺盐型阳离子淀粉抑铁效果较好。

关键词: 褐铁矿, 反浮选, 羧甲基淀粉钠, 普通可溶性淀粉, 叔胺盐型阳离子淀粉, 抑制剂, 电位

Abstract: In order to determine a certain kind of effective inhibitor adopted in reverse flotation process of a limonite mine in Xinjiang,the optimum test on the inhibitor of reverse flotation were carried out. The inhibition mechanism of the inhibitor was studied through surveying the surface ζ potentials of limonite under the condition of three different types of amyloid inhibitor. The results indicated that:①Under acidic conditions,the inhibit effect of iron is weakened orderly from sodium carboxymethyl starch,soluble starch to tertiary ammonium cationic starch. Under alkaline conditions,the inhibit effect of iron will be declined from tertiary ammonium cationic starch,soluble starch to sodium carboxymethyl starch. ②Taking sodium carboxymethyl starch with best inhibiting effect as inhibitor,iron ore concentrate with grade of 60.79% and recovery of 79.96% was obtained by adopting the process of one-roughing,two-cleaning,one scavenging and middles back to the flow-sheet in turn. ③The limonite ore with positive surface charges absorbs much sodium carboxymethyl starch(anionic starch) under acidic condition,which is the reason for the excellent inhibit effect on iron in acidic environment; The limonite ore with negative surface charges absorbs much tertiary ammonium cationic starch under alkaline condition,which is the reason for excellent inhibit effect on iron in alkaline environment.

Key words: Limonite, Reverse flotation, Sodium carboxymethyl starch, Soluble starch, Tertiary ammonium cationic starch, Inhibitor, Potential