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金属矿山 ›› 2014, Vol. 43 ›› Issue (10): 51-55.

• 矿物工程 • 上一篇    下一篇

十二胺聚氧乙烯醚对石英的捕收性能

刘安,樊民强   

  1. 太原理工大学矿业工程学院,山西 太原 030024
  • 出版日期:2014-10-15 发布日期:2015-05-19

Study of Dodecyl-amine Ethoxylate Collecting Performance on Quartz

Liu An,Fan Minqiang   

  1. College of Mining Technology,Taiyuan University of Technology,Taiyuan 030024,China
  • Online:2014-10-15 Published:2015-05-19

摘要: 通过石英单矿物浮选试验和实际磁铁矿石磁选精矿反浮选试验,比较了十二胺聚氧乙烯醚与十二胺和十二烷基丙基醚胺对石英的捕收性能,并通过吸附热、吸附量和吸附过程焓变的测定比较了3种捕收剂与石英表面作用的强弱。单矿物浮选试验结果表明,3种捕收剂最适宜的矿浆pH条件均为6~8,但无论矿浆pH如何变化,十二胺聚氧乙烯醚对石英的捕收能力都强于另两种捕收剂。实际矿样反浮选试验结果显示,十二胺聚氧乙烯醚可在比另两种捕收剂更低的用量下获得比另两种捕收剂更好的分选指标,说明十二胺聚氧乙烯醚不仅捕收能力强,而且选择性好。吸附热、吸附量和吸附焓变测定结果显示,不同pH下3种捕收剂在石英表面的吸附都是自发进行的,且均为物理吸附,但十二胺聚氧乙烯醚在各pH下与石英表面的吸附作用都比另两种捕收剂强,从而有力地支持了浮选试验所得结果。

关键词: 十二胺聚氧乙烯醚, 石英, 捕收性能, 吸附

Abstract: Pure quartz flotation experiments and reverse flotation of practical concentrate from magnetic separation of magnetite are conducted in order to compare the collecting ability of dodecylamine,dodecyl-propyl ether amine and dodecyl-amine ethoxylate on quartz.The adsorption heat,adsorption quantity,and the adsorption enthalpy are analyzed to compare the intensity of the three collectors to quartz surface.Pure mineral flotation results indicated that,the optimum pH for the three collectors is 6~8,and collecting ability of dodecyl-amine ethoxylate is better than the other two collectors at any pH value.Reverse flotation results of the practical sample showed that,better performance can be obtained by using dodecyl-amine ethoxylate on a lower dosage than the other two,which revealed that dodecyl-amine ethoxylate not only has higher collecting ability but also better selectivity.The adsorption heat,adsorption quantity,and the adsorption enthalpy analysis show that the adsorption of the three collectors on quartz is spontaneous,and all belongs to physical adsorption.The adsorption performance of dodecyl-amine ethoxylate on quartz is better than the other two at any pH value,which support the flotation results well.

Key words: Dodecyl-amine ethoxylate, Quartz, Collecting ability, Adsorption