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金属矿山 ›› 2019, Vol. 48 ›› Issue (04): 58-63.

• 矿物工程 • 上一篇    下一篇

微细粒鲕状赤铁矿磁化絮凝行为与机理研究

周文波1,2,3,向军1,李艾强1,李青青1,齐放1,陈庭阔1   

  1. 1. 武汉科技大学资源与环境工程学院,湖北 武汉 430081;2. 省部共建耐火材料与冶金国家重点实验室,湖北 武汉 430081;3. 冶金矿产资源高效利用与造块湖北省重点实验室,湖北武汉 430081
  • 出版日期:2019-04-15 发布日期:2019-05-13
  • 基金资助:

    * 省部共建耐火材料与冶金国家重点实验室青年基金项目(编号:2018QN19)。

Study on Magnetization Flocculation Behavior and Mechanism of Micro-grained Oolitic Hematite

Zhou Wenbo1,2,3,Xiang Jun1,Li Aiqiang1,Li Qingqing1,Qi Fang1,Chen Tingkuo1   

  1. 1. College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081,China; 2. State Key Laboratory of Refractory and Metallurgy, Wuhan 430081,China; 3. Hubei Key Laboratory for Ef?cient Utilization and Agglomeration of Metallurgic Mineral Resources,Wuhan 430081,China
  • Online:2019-04-15 Published:2019-05-13

摘要: 为提高赤铁矿絮凝浮选指标,分别采用磁化水、磁化矿浆和磁化淀粉3种磁化方式对赤铁矿进行絮凝沉降,考察磁处理方式对絮凝效果的影响。结果表明,3种磁化方式均能提高鲕状赤铁矿絮凝沉降率。光学显微镜分析结果显示,经过磁化处理后的絮团较未磁化时表观粒径更大,结构更加紧密,同时观察到絮团周围分散着透明的石英颗粒,说明磁化处理能够显著促进微细粒赤铁矿选择性絮凝。在磁化水、磁化矿浆和磁化淀粉3种磁化方式作用下赤铁矿颗粒表面ζ电位均随着磁化时间的增加而降低,ζ电位的变化趋势与鲕状赤铁矿在不同磁化条件下沉降率的变化规律一致。3种磁化方式对微细粒赤铁矿的絮凝过程符合扩展的DLVO理论,其絮凝机理为:磁化处理能在不同程度上降低赤铁矿颗粒表面ζ电位,进而降低了微细粒赤铁矿颗粒间的双电层排斥力,降低了颗粒间的势能垒。

关键词: 鲕状赤铁矿, 磁化处理, 絮凝行为, &zeta, 电位

Abstract: To increase the index of hematite flocculation flotation, magnetized water,magnetized pulp and magnetized starch were used to flocculate and settle hematite. Effects of magnetization treating on flocculate were investigated. The results show that all of the three magnetization modes can improve the flocculation settlement rate of oolitic hematite. The results of optical microscope analysis showed that it can be clearly seen that the floc size after the magnetization treatment is larger and more compact than that of the unmagnetized,at the same time, transparent quartz particles dispersed around the floc were observed, indicating that the magnetization treatment can significantly promote the selective flocculation of micro-grained hematite. Under the three magnetization modes of magnetized water,magnetized ore pulp,and magnetized starch,the surface potential of hematite particles decreased with the increase of magnetization time, and the variation trend of the Zeta potential was consistent with that of the sedimentation rate of oolitic hematite under different magnetization conditions. The flocculation mechanism of the fine-grained hematite after treated by three magnetization modes is in line with the extended DLVO theory.The flocculation mechanism is: the magnetization treatment can reduce the Zeta potential of the hematite in varying degrees,thereby reducing the double electrical layer repulsive force and potential energy barrier among the fine-grained hematite particles.

Key words: Oolitic hematite, Magnetization treatment, Flocculation behavior, Zeta potential