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金属矿山 ›› 2021, Vol. 50 ›› Issue (03): 116-123.

• 矿物工程 • 上一篇    下一篇

西藏林芝某含镓矽卡岩型白钨矿选矿工艺研究

李代会   

  1. 甘肃省有色金属地质勘查局兰州矿产勘查院,甘肃 兰州 730046
  • 出版日期:2021-03-15 发布日期:2021-03-17

Study on the Beneficiation Processing of A Gallium-Containing Skarn-Type Scheelite in Linzhi, Tibet

LI Daihui   

  1. Lanzhou Mineral Survey Institute, Gansu Nonferrous Metal Geological Survey Bureau, Lanzhou 730046, China
  • Online:2021-03-15 Published:2021-03-17

摘要: 西藏某矽卡岩型白钨矿石中WO3品位为0.52%,镓的含量为19.08 g/t。白钨矿嵌布粒度较粗,属于中粗粒嵌布。为制定合理的选矿工艺流程,选取具有代表性的矿石样品进行了选矿工艺试验,同时采用浸 出工艺探索了伴生元素镓的回收。试验结果表明:①矿石在磨矿细度为-0.074 mm占75.0%的条件下,以水玻璃为抑制剂,733为捕收剂,碳酸钠为调整剂,经“1粗2精2扫”的闭路试验,可获得WO3品位12.34%、WO3回 收率64.91%的钨粗精矿。②以钨粗精矿为给矿,经钨加温精选闭路试验流程,可获得WO3品位66.20%、WO3作业回收率95.12%的钨精矿。③镓作为伴生元素,其回收的最佳浸出条件为:搅拌温度90 ℃,H2SO4用量350 g/L,浸出时间6 h,助浸剂CaF2用量2.5 g,液固比8∶1,搅拌速度300 r/min,此时,镓的浸出率为62.55%。

关键词: 矽卡岩型, 白钨矿, 浮选, 加温精选,

Abstract: The WO3 grade in a skarn scheelite in Xizang province is 0.52% and the gallium content is 19.08 g/t. The scheelite is of coarse grain size and belongs to medium-coarse grain dissemination. In order to develop a reasonable beneficiation process, representative ore samples were selected for beneficiation process tests, and the recovery process of associated element gallium was explored using leaching process. The test results showed that: ① under the condition of grinding fineness of -0.074 mm accounting for 75.0%, sodium silicate as inhibitor, 733 as collector and sodium carbonate as regulator, tungsten coarse concentrate with WO3 grade of 12.34% and WO3 recovery rate of 64.91% was obtained through the closed-circuit test of one roughing, two cleaning and two scavenging. ② Tungsten concentrate with WO3 grade of 66.20% and WO3 recovery rate of 95.12% was obtained through the closed-circuit test process of tungsten warming cleaning with coarse tungsten coarse concentrate as feeding ore. ③ The optimal leaching conditions of gallium as a associated element are as follows: stirring temperature of 90 ℃, H2SO4 dosage of 350 g/L, leaching time of 6 h, leach aid agent CaF2 dosage of 2.5 g, liquid-solid ratio of 8∶1, stirring speed of 300 r/min. The leaching rate of gallium is 62.55% in the best condition.

Key words: skarn type, scheelite, flotation, warming cleaning, gallium