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金属矿山 ›› 2023, Vol. 52 ›› Issue (09): 269-274.

• 综合利用 • 上一篇    下一篇

流态胶凝材料胶结铁尾矿的充填性能研究

华 磊1 徐 亮1 李家茂1 樊传刚1 李圣军1 李正昊1 樊 曦2
  

  1. 1. 安徽工业大学材料科学与工程学院,安徽 马鞍山 243032;2. 安徽省融工博大环保技术材料研究院有限公司,安徽 马鞍山 243000
  • 出版日期:2023-09-15 发布日期:2023-11-03
  • 基金资助:
    安徽高校协同创新项目(编号:GXXT-2019-028)。

Filling Performances of Iron Tailings Cemented by Fluid Cementing Materials

HUA Lei1 XU Liang1 LI Jiamao1 FAN Chuan′gang1 LI Shengjun1 LI Zhenghao1 FAN Xi2 #br#   

  1. 1. School of Materials Science and Engineering,Anhui University of Technology,Maanshan 243032,China;2. Anhui Ronggong Boda Environmental Protection Technology and Materials Research Institute Co. ,Ltd. ,Maanshan 243000,China
  • Online:2023-09-15 Published:2023-11-03

摘要: 为实现用原状固废(钛石膏)的流态胶凝材料替代粉末胶凝材料进行铁尾矿胶结充填,简化胶凝材料制 作流程,降低充填成本,采用流动度试验、强度试验和吸水率试验研究了两种胶凝材料胶结铁尾矿试样的宏观物理性 能,并利用 XRD 和 SEM 对其胶结铁尾矿的固化机理进行了分析。 研究结果表明:在尾矿固含量为 70%、胶尾比为 1 ∶10 时,粉末胶凝材料胶结试样的 3 d 抗压强度(0. 87 MPa)比流态胶凝材料约高出 0. 3 MPa,但两种胶凝材料胶结试 样的 7 d 抗压强度差别在减小,28 d 抗压强度并无明显差别。 加入流态胶凝材料的充填尾矿流动度较加入粉末胶凝 材料的充填尾矿提高了 7. 4%,既有利于泵送充填又不影响试样 28 d 的尾矿胶结体力学性能。 XRD 和 SEM 分析表 明,流态胶凝材料的水化反应更有利于胶结体中钙矾石的生长。

关键词: 流态胶凝材料, 充填开采, 流动度, 抗压强度

Abstract: In order to simplify the process of cementitious material production and reduce the cost of filling,the fluid cementitious materials (FCM) were used to replace powder cementitious materials (PCM) for the solidification of iron tailings. The properties were investigated using fluidity tests,strength tests and water absorption tests for the specimens of solidified iron tailing (SIT) with two kinds of cementitious materials of PCM and FCM. The binding mechanism of SIT was analyzed using XRD and SEM techniques. For the specimen of SIT with the solid tailing content being 70% and the cement-to-tail ratio being 1 ∶10,the 3-day compressive strength (0. 87 MPa) of the specimens using PCM as tailing binder was about 0. 3 MPa higher than that using FMC. The difference of 7 d compressive strength was decreasing between two SIT specimens with PCM and FCM,and there was no significant difference for their 28 d compressive strengths. The flowability of the filling tailing with the addition of FCM was increased by 7. 4% compared to that with the addition of PCM. It indicated that the using of FCM could facilitate pumping and filling of iron tailing slurry without affecting the 28 d mechanical properties of SIT′s. XRD and SEM analysis showed that the hydration reaction of FCM was more benefit to the growth of ettringite.

Key words: fluid cementitious material,filling mining,fluidity,compressive strength