欢迎访问《金属矿山》杂志官方网站,今天是 分享到:
×

扫码分享

金属矿山 ›› 2025, Vol. 54 ›› Issue (7): 217-222.

• 安全与环保 • 上一篇    下一篇

某细粒金尾矿充填材料的性能与浸出液水质研究 

胡  敏1,2,3   李浩然1,3    

  1. 1. 四川省城市污泥建材资源化利用工程研究中心,四川 德阳 618000;2. 重庆交通大学土木工程学院,重庆 400074; 3. 四川建筑职业技术学院德阳市建材环保资源化工程研究中心,四川 德阳 618000
  • 出版日期:2025-07-15 发布日期:2025-08-14
  • 通讯作者: 李浩然(1982—),女,副教授,硕士。
  • 作者简介:胡  敏(1986—),女,副教授,硕士。
  • 基金资助:
    四川省自然科学基金—面上项目(编号:2024NSFSC0133);德阳市社会发展领域重点研发项目(编号:2022SZZ006);四川建筑职业技 术学院院级课题项目(编号:2023KJ13)。 

Properties of Backfill Material with a Fine Gold Tailings and Water Quality of Leaching Solution

HU Min 1,2,3   LI Haoran 1,3    

  1. 1. Sichuan Engineering Research Center of Urban Sludge For Building Materials Resource Utilization,Deyang 618000,China; 2. School of Civil Engineering,Chongqing Jiaotong University,Chongqing 400074,China;3. Deyang Research Center of Building Materials and Environmental Resource Engineering Technology,Sichuan College of Architectural Technology,Deyang 618000,China
  • Online:2025-07-15 Published:2025-08-14

摘要: 以四川平武大包山金尾矿与硅酸盐水泥为原材料,采用一步法制备了金尾矿充填材料,分析了灰砂比、 料浆质量浓度对充填材料的流动性、泌水率、力学性能的影响规律;以蒸馏水为充填材料浸提剂,以浸出液 pH、悬浮 物、化学需氧量(COD)以及氨氮、总磷、氟化物的含量为评价指标,考察了充填材料对地下水的影响。 结果表明:金尾 矿充填材料强度的发展以水泥水化为主,水泥水化后的碱性环境激发了尾矿的水化;随着灰砂比降低、料浆质量浓度 增加,流动性变差,泌水率降低,抗压强度减小;所有浸出液水质指标均符合《地下水质量标准》 (GB/ T 14848—2017) 要求,对地下水无二次污染风险;采用功效系数法对 9 个性能指标进行的综合评分,认为料浆质量浓度为 68%、灰砂 比为 1 ∶6 所对应的系统综合性能最佳。 微观分析显示充填材料强度主要来自 C-S-H 凝胶。 

关键词: 金尾矿  流动性  抗压强度  水质分析  功效系数法

Abstract: With gold mine tailings in Sichuan Pingwu Dabaoshan and Portland cement as raw materials,the backfill materials with gold tailing were prepared using a one-step method. The effects of various cement / sand ratios and slurry concentrations on rheological properties,bleeding rate,mechanical property were studied. Using distilled water as the extraction agent,the pH,suspended matter,chemical oxygen demand(COD),ammonia nitrogen,total phosphorus and fluoride of the leaching solution were investigated for the influence of backfill materials on groundwater. The results show that the strength development of gold tailings filling material is mainly cement hydration,and the alkaline environment after cement hydration stimulates the hydration of tailings. With the decrease of cement sand ratio and the increase of slurry mass concentration,the fluidity becomes worse,the bleeding rate decreases,and the compressive strength decreases. The water quality of the leaching solution was all much less than the standard limits according to groundwater quality standards of GB/ T 14848—2017 without any secondary pollution. The efficacy coefficient method was used to score the nine indexes. It is believed that the system′s overall performance is optimal when the slurry mass concentration is 68% and the cement-sand ratio is 1 ∶6. The microstructure of the backfill material was dominated by C-S-H gel resulting in good mechanical properties. 

Key words: gold tailings,fluidity,compressive strength,the water quality analysis,efficacy coefficient method 

中图分类号: