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Metal Mine ›› 2013, Vol. 42 ›› Issue (11): 158-160+163.

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Research of Vanadium Extraction from Vanadium-bearing Intermediate Slag Mixed into Tailings with Sodium Roasting

Li Xiumin1,Zhang Yimin1,2,Huang Jing1,Liu Tao1,Bao Shenxu1   

  1. 1.School of Resources and Environmental Engineering,Wuhan University of Technology;2..Hubei Key Laboratory of Mineral Resources Processing and Environment
  • Online:2013-11-15 Published:2014-01-26

Abstract: To solve problems in vanadium recovery with high efficiency and low consumption from vanadium-extracted tailings,taking vanadium slags from a steel company as raw material,vanadium-bearing intermediate slag was concentrated by adopting the process of the acid leaching of vanadium-extracted tailings and vanadium deposition with acid leaching solution,and then the influence of the amount of intermediate slags mixed into tailings to the sodium roasting with vanadium-bearing slag and water leaching rate of vanadium was studied. The mechanism of generating this law was discussed. The results showed that the vanadium-bearing intermediate slag replacing the vanadium-extracted tailings back to the process of vanadium extraction with sodium roasting could decrease the decomposition temperature of vanadium-bearing spinel,and reduce the degree of sintering on roasting slag. It also makes the oxidation of vanadium and promote the reaction of vanadium in vanadium-bearing spinel with Sodium carbonate to generate soluble sodium vanadate more easily,and finally realize vanadium recycling with high efficiency and low consumption.

Key words: Vanadium-bearing slag, Vanadium-extracted tailings, Intermediate slag, Sodium roasting, Water leaching rate of vanadium