Abstract: There is 538.51 mg/L Sb and 395.91 mg/L Cu in a leachate from a smelting plant in Hechi，Guangxi Province.Antimony recovery by hydrolysis precipitation method，copper recovery by Na2S precipitation from residual liquid from antimony precipitation on the leachate experiment results showed that antimony hydrolysis precipitation at the stirring speed of 150 r/min，reaction at 56 ℃for 20 min，final pH=3.15，precipitation antimony products with antimony grade and precipitation rate of 10.35%，98.23% is obtained.Residual liquid from antimony precipitation with Na2S dosage of 2.5 g/L，stirring speed of 150 r/min，reaction at 50 ℃for 10 min，stewing for 20 min and then enduring filtration，precipitation copper products with copper grade and precipitation rate of 36.92%，98.38% is obtained.The tests proved that fractional precipitation is a feasible method to recycle antimony，copper from the leachate.

Key words: Leachate, Antimony recovery by hydrolysis precipitation, Copper recovery by Na₂S precipitation,Sb(OH)₃, CuS