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Metal Mine ›› 2019, Vol. 48 ›› Issue (02): 97-101.

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Flotation Behaviors and Mechanisms of a Amphoteric Chelated Type Collector DRQ-3 for Spodumene Flotation

Xie Ruiqi1,2, Zhu Yimin1,2, Han Xyuqian1,2, Zhang Meng1,2, Li Yanjun1,2   

  1. 1. School of Resource and Civil Engineering,Northeastern University,Shenyang 110819,China;2. National-Local Joint Engineering Research Center of Refractory Iron Ore Resources Efficient Utilization Technology,Shenyang 110819, China
  • Online:2019-02-25 Published:2019-04-08

Abstract: The floatation experiments of spodumene were carried out by a new type of collector DRQ-3 synthesizing in the laboratory. The adsorption mechanism of DRQ-3 collector on spodumene surface was established by Zeta potential measurements, Fourier transforminfrared (FT-IR) spectrum, in conjunction with the results of flotation test. The results show that: in the condition of 26 ℃, pulp natural pH (pH = 8.5), spodumene flotation recovery rate can reach 94.50% with 50 mg/L DRQ - 3 as collector, which indicated that DRQ-3 has a strong ability of collecting for spodumene. The results of FT-IR spectroscopy showed that there was a chemical adsorption between the collector DRQ-3 and spodumene. According to the crystal structure of spodumene, it was speculated that the chemical reaction between the spodumene and DRQ-3 was mainly depended on Al3+ and the active group in DRQ-3. The results of Zeta potential measurement indicated that the electrostatic adsorption between spodumeneand DRQ-3 was impossible. Combining with the results of FT-IR spectroscopy, it was revealed that the DRQ-3 collector had adsorbed on the spodumene in the form of chemical adsorption.

Key words: amphoteric chelated collectors, Spodumene, Flotation performance, Adsorption mechanism