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Metal Mine ›› 2020, Vol. 49 ›› Issue (04): 200-205.

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Emergency Remediation of Heavy Metal Contaminated Soil by Nanobubbles Flotation

Fu Kaibin1,2 Qin Tianbang1 Long Meiqiao1 Hou Puyao1 Zhong Qiuhong1 Du Mingxia1   

  1. 1. Key Laboratory of Solid Waste Treatment and Resource Recycle, Ministry of Education, Mianyang 621010, China; 2. Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China
  • Online:2020-04-15 Published:2020-04-30

Abstract: A self-made nanobubble air flotation device was used as an experimental instrument to simulate the soil heavy metal pollution event caused by the leakage of solution containing Cu2+, Cd2+, Ni2+, Pb2+, Zn2+ and Cr3+, and the effects of parameters,such as grinding fineness and pH value on the removal efficiency of heavy metal ions were investigated to determine the rapid remediation process of heavy metal contaminated soil by nanobubbles flotation. The results of research showed that when the dosage of ammonium sulfate is 30 kg/t, the dosage of Na2S is 36 kg/t, the dosage of butyl xanthate is 2 500 g/t, pH value is 8.0 and flotation time is 60 min, the removal rates of Cu2+, Cd2+, Ni2+, Pb2+, Zn2+ and Cr3+ in the contaminated soil were 90.08%, 87.92%, 85.95%, 84.77%, 78.85% and 75.58%, respectively after "one roughing and three scavenging". The contents of Cu2+, Cd2+, Ni2+, Pb2+, Zn2+ and Cr3+in the foam products were 12.01×104 mg/kg, 11.72×104 mg/kg, 11.46×104 mg/kg, 11.30×104 mg/kg, 10.51×104 mg/kg, 10.08×104 mg/kg, respectively, which reached the quality requirements of sulfide concentrate and had comprehensive recovery value. The technological process obtained from the study has guiding significance for the emergency remediation of heavy metal contaminated soil.

Key words:  Heavy metal, Contaminated soil, Nanobubbles flotation, Emergency remediation