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金属矿山 ›› 2010, Vol. 39 ›› Issue (05): 64-67.

• 矿物工程 • 上一篇    下一篇

鄂西某高磷鲕状赤铁矿磁化焙烧及浸出除磷试验

李育彪, 龚文琪, 辛桢凯, 皮科武, 胡纯   

  1. 武汉理工大学
  • 出版日期:2010-05-15 发布日期:2010-11-09
  • 基金资助:

    “十一五”国家科技支撑计划项目(编号:2007BAB15B01),国家重点基础研究发展计划(973计划)项目(编号:2004CB619204)。

Research on Magnetic Roasting and Leaching Dephosphorization of High-phosphorus Oolitie Hematite in Western Hubei

Li Yubiao,Gong Wenqi,Xin Zhenkai,Pi Kewu,Hu Chun   

  1. Wuhan University of Technology
  • Online:2010-05-15 Published:2010-11-09

摘要: 针对鄂西某高磷鲕状赤铁矿(铁品位43.50 %),在实验室条件下采用磁化焙烧—磁选工艺获取铁精矿,并对该铁精矿进行酸浸、生物浸出除磷试验。研究结果表明,在焙烧温度850 ℃,焙烧时间25 min,还原剂用量为矿石质量的5%,磨矿时间4 min,磁场强度120 kA/m条件下,得到铁精矿铁品位为54.92%,铁回收率为86.78%,P含量为0.83%;酸浸试验中矿浆浓度2%,分别用0.1 mol/L的H2SO4,HNO3,HCl,草酸(C2H2O4),柠檬酸(C6H8O7) 除磷,其中H2SO4除磷提铁效果最佳,铁精矿品位为57.98%,回收率为96.47%,除磷率为95.30%;生物浸出试验中矿浆浓度2%,用嗜酸氧化亚铁硫杆菌(At..f菌)对铁精矿作用后,磷含量为0.23%,用黑曲霉菌滤液对铁精矿作用后,磷含量为0.20%。

关键词: 鲕状赤铁矿, 高磷铁矿石, 磁化焙烧, 酸浸, 生物浸出, 除磷

Abstract: Roasting -magnetic separation was used to treat a high-phosphorus oolitic hematite in western Hubei(iron grade at 43.50%),dephosphorization methods,including acid leaching and bioleaching,were used for the iron concentrate.The results showed that,under the condition of roasting at 850 ℃ for 25 min,reductant to ore ratio of 5%,grinding time of 4min,magnetic field strength 120 kA/m,the iron concentrate grade was 54.92%,iron recovery rate was 86.78%,with P 0.83%; in the acid leaching test,pulp density was 2%,with 0.1 mol /L of H2SO4,HNO3,HCl,C2H2O4,C6H8O7 for phosphorus removal,in which H2SO4 was the most effective,and the iron grade,recovery rate,phosphorus removal rate were 57.98%,96.47%,95.30%,respectively; in the bioleaching test,pulp density was 2%,with the filtrate of the Acidophilic Thiobacillus ferrooxidans (At.f)  and the  Aspergillus niger  on iron concentrate ore,the phosphorus content were  0.23%, 0.20%, respectively.

Key words: Oolitie Hematite, High Phosphorus ore, Magnetic roasting, Acid leaching, Bioleaching, Dephosphorization